A novel Schiff base bearing dopamine groups with tripodal structure. Synthesis and its salen/salophen-bridged Fe/Cr(III) capped complexes

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dc.contributor.authorKocyigit, Ozcan
dc.date.accessioned2020-03-26T18:41:02Z
dc.date.available2020-03-26T18:41:02Z
dc.date.issued2013
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThis work presents the synthesis of a novel Schiff base and its complexation properties with Fe(III) and Cr(III). A Schiff base bearing dopamine (TRDPA) was synthesized using dopamine hydrochloride and 1,3,5-tris (formylphenoxymethyl)benzene in methanol media. The prepared TRDPA was then reacted with four new trinuclear Fe(III) and Cr(III) complexes involving tetradenta Schiff bases N,N-bis(salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine-(salophenH(2)). The structures of these compounds were characterized through H-1 NMR, C-13 NMR, FT-IR, thermal analysis (TG), elemental analysis, and magnetic susceptibility measurements. The complexes were also characterized as low-spin distorted octahedral Fe(III) and COB) bridged by a catechol group. (C) 2012 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipResearch Foundation of The Selcuk University (BAP)Selcuk Universityen_US
dc.description.sponsorshipWe thank the Research Foundation of The Selcuk University (BAP) for financial support of this worken_US
dc.identifier.doi10.1016/j.molstruc.2012.09.008en_US
dc.identifier.endpage74en_US
dc.identifier.issn0022-2860en_US
dc.identifier.issn1872-8014en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage69en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.molstruc.2012.09.008
dc.identifier.urihttps://hdl.handle.net/20.500.12395/29178
dc.identifier.volume1034en_US
dc.identifier.wosWOS:000314554800010en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofJOURNAL OF MOLECULAR STRUCTUREen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectComplexationen_US
dc.subjectTrisaldehydeen_US
dc.subjectSchiff baseen_US
dc.subjectDopamineen_US
dc.titleA novel Schiff base bearing dopamine groups with tripodal structure. Synthesis and its salen/salophen-bridged Fe/Cr(III) capped complexesen_US
dc.typeArticleen_US

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