Synthesis, spectroscopic and cyclic voltammetry studies of novel azacrown ether containing vic-dioxime ligand and its Ni(II), Cu(II), Co(II), Cd(II) and Zn(II) complexes
Küçük Resim Yok
Tarih
2013
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
SPRINGER
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, the novel vic-dioxime ligand (3) and its Ni(II), Cu(II), Co(II), Cd(II) and Zn(II) complexes (4-8) were synthesized for the first time by condensation reactions of N-(4-aminophenyl)aza-15-crown-5 (1) and anti-chlorophenylchloroglyoxime (2). All of these new compounds were characterized by the elemental analysis, Fourier transform infrared, ultraviolet-visible, mass spectrometry, H-1 NMR, C-13 NMR and magnetic susceptibility measurements. The electrochemical properties of the ligand and its complexes have been investigated by cyclic voltammetry at the glassy carbon electrode in 0.1 M TBATFB in DMSO.
Açıklama
Anahtar Kelimeler
vic-Dioxime, Metal complexes, Azacrown ether, Electrochemical properties
Kaynak
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
WoS Q Değeri
Q2
Scopus Q Değeri
Q3
Cilt
77
Sayı
01.04.2020
