Novel Calix[4]arene-based Polymeric Catalysts as Acyltransferase Enzyme Mimics

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dc.contributor.authorTabakcı, Begüm
dc.contributor.authorYılmaz, Mustafa
dc.contributor.authorBedük, A. Dincer
dc.date.accessioned2020-03-26T18:30:56Z
dc.date.available2020-03-26T18:30:56Z
dc.date.issued2012
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractMonomeric and polymeric calix[4]arenes containing imidazole or triazole functionalities were synthesized. The enzymatic performance of these calix[4]arenes was evaluated by comparing the MichaelisMenten kinetics for the hydrolysis reaction of p-nitrophenyl acetate. The results indicate that the newly synthesized both monomeric and polymeric calix[4]arenes could be used as acyltransferase mimics. The results of monomeric mimics showed that the calix[4]arenes containing imidazole groups are more efficient acyltransferase mimics than triazole-bonded ones. In the case of carboxylic acid-bonded mimic, it was also observed that H-bond contributed to increasing of catalytic yield. The catalytic studies of polymeric mimics demonstrated that the calixarene contents of polymers were very important for their hydrolytic activities. Moreover, the recyclability studies of some polymeric calix[4]arenes revealed that Merrifield resin was the best supporting material for the polymeric catalysts. (c) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012en_US
dc.description.sponsorshipResearch Foundation of Selcuk University, Konya, TurkeySelcuk University [07101026]en_US
dc.description.sponsorshipThe authors thank the Research Foundation of Selcuk University, Konya, Turkey for financial support (Grant Number: 07101026) of this work produced from Begum Tabakci's PhD Thesis.en_US
dc.identifier.citationTabakçı, B., Yılmaz, M., Bedük, A. D., (2012). Novel Calix[4]arene-based Polymeric Catalysts as Acyltransferase Enzyme Mimics. Journal of Applied Polymer Science, 125(2), 1012-1019. Doi 10.1002/app.36344
dc.identifier.doi10.1002/app.36344en_US
dc.identifier.endpage1019en_US
dc.identifier.issn0021-8995en_US
dc.identifier.issn1097-4628en_US
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1012en_US
dc.identifier.urihttps://dx.doi.org/10.1002/app.36344
dc.identifier.urihttps://hdl.handle.net/20.500.12395/28260
dc.identifier.volume125en_US
dc.identifier.wosWOS:000302350300022en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorTabakcı, Begüm
dc.institutionauthorYılmaz, Mustafa
dc.institutionauthorBedük, A. Dincer
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofJournal of Applied Polymer Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectcalix[4]arenesen_US
dc.subjectpolymeric calixarenesen_US
dc.subjectenzyme-mimicen_US
dc.subjectMichaelis-Mentenen_US
dc.subjectcatalysten_US
dc.subjectimidazoleen_US
dc.subjecttriazoleen_US
dc.titleNovel Calix[4]arene-based Polymeric Catalysts as Acyltransferase Enzyme Mimicsen_US
dc.typeArticleen_US

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