Hosseınzadeh, AIrez, G2020-03-262020-03-261991Hosseınzadeh, A., Irez, G., (1991). Synthesis of Five New Substituted Aryldiaminoglyoximes and Their Complexes with Copper(II), Nickel(II) and Cobalt(II). Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 21(2), 301-312. DOI: 10.1080/155331791080201840094-5714https://dx.doi.org/10.1080/15533179108020184https://hdl.handle.net/20.500.12395/16117anti-Chloroaminoglyoxime (CAGH2) has been synthesized by chlorination of anti-aminoglyoxime. The reaction of CAGH2 with substituted aromatic amines in ethanol at -15-degrees-C gives the unsymmetrical vic-dioximes, namely, N-(phenyl)diaminoglyoxime (PDGH2), N-(benzyl)diaminoglyoxime (BDGH2), N-1-naphthyl)diaminoglyoxime (NDGH2), N-(2-pyridyl)diaminoglyoxime (PYDGH2) and N-(1-1'-biphenyl-4-amino-4')diaminoglyoxime (BBGH2). All these dioximes are in the trans-anti-form according to IR and H-1-NMR data. The complexes of these five ligands with Cu(II), Ni(II) and Co(II) are square-planar. H-1-NMR, IR and UV-visible data of new compounds are given.en10.1080/15533179108020184info:eu-repo/semantics/closedAccessArticle212301312N/AWOS:A1991FJ28700011N/A