Uysal, SabanCoskun, AhmetKoc, Ziya ErdemUcan, H. Ismet2020-03-262020-03-2620081060-1325https://dx.doi.org/10.1080/10601320802222616https://hdl.handle.net/20.500.12395/22662omega-Isonitrosoacetophenone (1), phenylglyoxime (2), chlorophenylglyoxime (1), dopaminophenylglyoxime (3) and [(salen/saloph)Fe](2)O (4) have been synthesized as described in the literature procedure. [Fe(III)(salen/saloph)dopaminophenylglyoxime)] (starting complexes) have been synthesized from dopaminophenylglyoxime and tetradentate schiff bases which contain dinuclear Fe(III) oxygen-bridges N,N'-bis(salicylidene)ethylenediamine (salenH(2)) and bis(salicylidene)-o-phenylenediamine (salophH(2)). The new heterotrinuclear complexes have been obtained from starting complexes and Co(II), Ni(II), Cu(II) salts. Then, heterotrinuclear vic-dioxime complexes containing BF(2)(+) capped have been synthesized. The complexes have been characterized as low-spin distorted octahedral Fe(III) bridged by o-hydroxyphenolic groups. The o-hydroxyphenolic groups play a role as bridges for weak antiferromagnetic intramolecular exchange. The structure of dioxime and its complexes were identified by using elemental analysis, ICP-AES, (1)H-NMR and IR spectral data.en10.1080/10601320802222616info:eu-repo/semantics/closedAccessBF(2)(+)-capped complexvic-dioximestransition metal complexessalensalophArticle459727732Q2WOS:000257526100006Q3