Erdemir, SerkanKocyigit, Ozcan2020-03-262020-03-2620180925-4005https://dx.doi.org/10.1016/j.snb.2018.06.019https://hdl.handle.net/20.500.12395/36507A new reactive and highly selective fluorescent sensor (CBA) containing 4-cyanobiphenyl and anthracene as two fluorophores was synthesized for the detection of Zn2+ and Al3+ ions. CBA exhibited an effectively selective and sensitive recognition towards Zn2+ and Al3+ ions through two different mechanisms (i.e. PET, C = N isomerization and hydrolysis) in EtOH-H2O (v/v = 95/5) over other cations. The complexation properties of CBA with Zn2+ and Al3+ ions were examined by UV-vis, H-1 NMR and FTIR experiments. This sensor showed high sensitivity for Zn2+ and Al3+ with detection limits (LOD) as low as 78.8 and 52.2 nM, respectively, and high selectivity through a 'turn-on' fluorescence response over the other tested metal ions. To check its applicability, an easy prepared test paper strip of CBA was produced for rapid and selective detection of Zn2+ and Al3+ ions. Also, the determination of Zn2+ and Al3+ in water samples was evaluated.en10.1016/j.snb.2018.06.019info:eu-repo/semantics/closedAccessAnthracene4-biphenylcarzbonitrileZincAluminumHydrolysisDual recognition of Zn2+ and Al3+ ions by a novel probe containing two fluorophore through different signaling mechanismsArticle2735661Q1WOS:000441519000008Q1