Durmaz, MustafaYılmaz, MustafaSirit, Abdülkadir2020-03-262020-03-2620111477-05201477-0539https://dx.doi.org/10.1039/c0ob00399ahttps://hdl.handle.net/20.500.12395/26871Two armed chiral calix[4]arenes 8-16 functionalized at the lower rim with chiral aminonaphthol units have been prepared and the structures of these receptors characterized by FTIR, H-1, and C-13, DEPT and COSY NMR spectroscopy and elemental analysis. The enantioselective recognition of these receptors with various carboxylic acids has been studied by H-1 NMR and UV/Vis spectroscopy. The receptors exhibited different chiral recognition abilities towards the enantiomers of racemic materials and formed 2 : 1 or 1 : 1 complexes between host and guest. It was also demonstrated that chiral calix[4]arenes 9 and 16 could be used as chiral NMR solvating agents to determine the enantiomeric purity of mandelic acid.en10.1039/c0ob00399ainfo:eu-repo/semantics/closedAccessSynthesis of chiral calix[4]arenes bearing aminonaphthol moieties and their use in the enantiomeric recognition of carboxylic acidsArticle9257158021063630Q1WOS:000285749800034Q1