Complexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine

Koc, Ziya ErdemUcan, H. Ismet2020-03-262020-03-2620081060-1325https://dx.doi.org/10.1080/10601320802458087https://hdl.handle.net/20.500.12395/22279Four new trinuclear Fe(III) and Cr(III) complexes involving tetradenta Schiff bases N,N'-bis(salicylidene)ethylenediamine-(salenH2) or bis(salicylidene)-o-phenylenediamine-(saloph H2) with 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazine (TNPI-TRIPOD) have been synthesized and characterized by means of elemental analysis carrying out 1H-NMR., IR spectroscopy, thermal analyses and magnetic susceptibility measurements. The complexes can also be characterized as high-spin distorted octahedral Fe(III) and Cr(III) bridged by nitro. The nitro play a role as bridges for weak anti-ferromagnetic intramolecular exchange.en10.1080/10601320802458087info:eu-repo/semantics/closedAccessSchiff basetriazinecyanuric chloridesalensalophmetal complexesComplexes of Iron(III) and Chrom(III) Salen and Saloph Schiff Bases with Bridging 2,4,6-tris(4-nitrophenylimino-4'-formylphenoxy)-1,3,5-triazineArticle451210741079Q2WOS:000260605800014Q3