Kahraman, AIrez, G2020-03-262020-03-2619960094-5714https://dx.doi.org/10.1080/00945719608004247https://hdl.handle.net/20.500.12395/16422Unsymmetric glyoximes which contain N-(2-methylpyridyl) on one side and amines or various aromatic amines, respectively, on the other side of the molecule were synthesized. N-(2-Methylpyridyl)aminoglyoxime was chlorinated by employing a method devised by us which is time and solvent dependent, and requires utilization of diethyl ether within a time period of 10-30 minutes. By reacting antichloro-N-(2-methylpyridyl)aminoglyoxime, with ammonia, aniline and benzylamine, respectively, the new ligands synthesized were N-(2-methylpyridyl)diaminoglyoxime (ALH(2)), N-(2-methylpyridyl)-N'-phenyldiaminoglyoxime (BLH(2)) and N-(2-methylpyridyl)-N'-benzyldiaminoglyoxime (CLH(2)). The structure of the ligands were determined employing H-1 NMR, IR spectroscopy and elemental analyses methods. The square-planar complexes of metal-ligand ratio of 1:2 were prepared by addition of Ni(II) and Pd(II) salt solutions into aqueous ligand solutions. The structure of these complexes were characterized by IR spectroscopy, elemental analyses and magnetic susceptibility measurements.en10.1080/00945719608004247info:eu-repo/semantics/closedAccessArticle2617991N/AWOS:A1996TU43400007N/A