Bhatti, Asif AliOguz, MehmetMemon, ShahabuddinYilmaz, Mustafa2020-03-262020-03-2620171053-05091573-4994https://dx.doi.org/10.1007/s10895-016-1953-6https://hdl.handle.net/20.500.12395/34984In the present work new naphthalene appended calix[4]arene (NAC4) i.e. 5,11,17,23-tetra-tert-butyl-25,27-di((2-amido(1-naphthlene)ethyl)-26,28-dihydroxy calix[4]arene (6) was designed and successfully synthesized. NAC4 was characterized by (HNMR)-H-1 and FTIR. To explore the complexation behavior and fluorescence response of NAC4, UV-visible and fluorescence studies were carried out with series of metal ions and anions that include solvatochromic effect, ion-ligand response and interference on absorption and fluorescence spectra. Results show that the NAC4 is highly Cu2+ and I(-)selective. The ligand ion interaction follow photoinduced electron transfer (PET) mechanism. The stiochiomatric ratio of ion-ligand was calculated as 1:1 by using Job's plot method and binding constant K-a values were calculated by using Benesi-Hildebrand equation as 1x10(3) and 8x10(2) M-1 with detection limit of 1.05x10(-5) and 4.0x10(-5) M for Cu2+ and I- respectively.en10.1007/s10895-016-1953-6info:eu-repo/semantics/closedAccessCalix[4] areneNaphthleneFluorescencePET, ion sensorArticle27126327027796629Q1WOS:000393753800024Q3