Taner, BilgeDeveci, PervinOzcan, EmineSolak, Ali Osman2020-03-262020-03-2620121388-31271573-1111https://dx.doi.org/10.1007/s10847-012-0131-yhttps://hdl.handle.net/20.500.12395/27690A new calix[4]pyrrole functionalized vic-dioxime, 3-(4-methyl-9,9,14,14,19,19-hexaethylcalix[4]pyrrole)benzoaminoglyoxime (LH2) was synthesized from anti-chloroglyoxime and 3-aminophenyl-calix[4]pyrrole at room temperature. The mononuclear complexes {nickel(II), copper(II) and cobalt(II)} of this vic-dioxime ligand were prepared and their structures were confirmed by elemental analysis, IR and UV-Vis spectrophotometry, magnetic susceptibility; the MS, H-1 and C-13 NMR spectra of the LH2 ligand and its Ni(II) complex were also recorded. The experimental results indicated that the ligand:metal ratio was 2:1 in the cases of Ni(II), Cu(II) and Co(II) complexes as is with most vic-dioximes. Electrochemical properties of the ligand, and its complexes were investigated in DMSO solution by cyclic voltammetry at 200 mV s(-1) scan rate.en10.1007/s10847-012-0131-yinfo:eu-repo/semantics/closedAccessOximevic-DioximeTransition metal complexCalix[4]pyrroleCyclic voltammetryArticle7401.04.2020391396Q3WOS:000306946700040Q2