Coskun, AhmetKarapinar, Emin2020-03-262020-03-2620081388-31271573-1111https://dx.doi.org/10.1007/s10847-007-9352-xhttps://hdl.handle.net/20.500.12395/226744-(Chloroacetyl)diphenyl thioether (1) was synthesized from chloroacetyl chloride and diphenyl thioether in the presence of AlCl3 as catalyst in a Friedel-Crafts reaction. Subsequently, its keto oxime (2) and glyoxime (3) derivatives were prepared. N-(4'-Benzo[15-crown-5]thiophenoxyphenylaminoglyoxime (H2L) and its sodium chloride complex (H2L center dot NaCl) were prepared from 4-(thiophenoxy)chlorophenylglyoxime (3), 4'-aminobenzo[15-crown-5] and sodium bicarbonate or sodium bicarbonate and sodium chloride. Ni(II), Co(II) and Cu(II) complexes of H2L and H2L center dot NaCl have a metal-ligand ratio of 1:2 and the ligand coordinates through the two N atoms, as do most of the vic-dioximes. The BF2-capped Ni(II) mononuclear complex of the vic-dioxime was prepared. The macrocyclic ligands and their transition metal complexes were characterized on the basis of FT-IR, H-1 NMR, C-13 NMR spectroscopy and elemental analyses data.en10.1007/s10847-007-9352-xinfo:eu-repo/semantics/closedAccessBF2+-capped complexcrown compoundsglyoximestransition metal complexesArticle6001.02.20205964Q3WOS:000252475000008Q3