Sevindir, Cahit H.Mirzaoğlu, Ramazan2020-03-262020-03-261993Sevindir, H. C., Mirzaoğlu, R., (1993). Synthesis and Complex Formation of Substituted Amino-P-tolylglyoximes of Unsymmetrical vic-Dioximes. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 23(5), 757-765. DOI: 10.1080/155331793080168580094-5714https://dx.doi.org/10.1080/15533179308016858https://hdl.handle.net/20.500.12395/16170anti-p underbar-Tolylchloroglyoxime (PTCGH2) has been synthesized by chlorination of anti-p underbar-tolylglyoxime. The reaction of PTCGH2 with p underbar-chloroaniline, o underbar-chloroaniline and m underbar-chloroaniline in ethanol between -10-degrees-C and -15-degrees-C gives unsymmetrical vic-dioximes, designated as: p underbar-chloroanilino-p underbar-tolylglyoxime (p underbar-CAPTGH2), o underbar-chloroanilino-p underbar-tolylglyoxime (o underbar-CAPTGH2), m underbar-chloroanilino-p underbar-tolylglyoxime (m underbar-CAPTGH2). The Ni(II) and Cu(II) complexes of these ligands are proposed to be square-planer, while the Co(II) complexes are proposed to be octahedral with water molecules as axial ligands. Structural assiguments are supported by H-1-NMR, IR and elemental analyses which are here in reported.en10.1080/15533179308016858info:eu-repo/semantics/closedAccessArticle235757765N/AWOS:A1993LB53100007N/A