Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4 '-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) Complexes

Koc, Ziya ErdemUysal, Saban2020-03-262020-03-2620111574-14431574-1451https://dx.doi.org/10.1007/s10904-011-9475-9https://hdl.handle.net/20.500.12395/26863Eight new trinuclear Fe(III)/Cr(III) complexes involving tetradentate (N2O2) and pentadentate (N3O2) Schiff bases of (salenH(2)), (salophenH(2)), (saldetaH(2)) and (salpyrH(2)) with 2,4,6-tris(4-carboxymethylenephenylimino-4'-formylphenoxy)-1,3,5-triazine were synthesized. The structure of ligand and complexes were identified using elemental and thermal analysis, magnetic susceptibility, and LC-MS, ICP-AES, H-1 NMR and FT-IR spectral data. All complexes are tripodal-trinuclear. The complexes are low-spin (S = 1/2) distorted octahedral salen- or salophen-capped Fe(III), high-spin (S = 5/2) distorted octahedral saldeta- or salpyr-capped Fe(III) and distorted octahedral (S = 3/2) salen-, salophen-, saldeta- or salpyr-capped Cr(III).en10.1007/s10904-011-9475-9info:eu-repo/semantics/closedAccessSalenSalophenSaldetaSalpyrSchiff bases-TriazineFe(III)N2O2N3O2Synthesis and Characterization of Tripodal Oxy-Schiff base (2,4,6-Tris(4-Carboxymethylenephenylimino-4 '-formylphenoxy)-1,3,5-triazine) and the Thermal and Magnetic Properties of its Fe(III)/Cr(III) ComplexesArticle213400406Q2WOS:000294804500002Q2