Hatay, ImrenSu, BinLi, FeiMendez, Manuel AlejandroKhoury, TonyGros, Claude P.Barbe, Jean-Michel2020-03-262020-03-2620090002-78631520-5126https://dx.doi.org/10.1021/ja904569phttps://hdl.handle.net/20.500.12395/23795Cobalt porphine (COP) dissolved in the organic phase of a biphasic system is used to catalyze O-2 reduction by an electron donor, ferrocene (Fc). Using voltammetry at the interface between two immiscible electrolyte solutions (ITIES), it is possible to drive this catalytic reduction at the interface as a function of the applied potential difference, where aqueous protons and organic electron donors combine to reduce O-2. The current signal observed corresponds to a proton-coupled electron transfer (PCET) reaction, as no current and no reaction can be observed in the absence of either the aqueous acid, COP, c, or O-2.en10.1021/ja904569pinfo:eu-repo/semantics/closedAccessArticle13137134531345919715275Q1WOS:000270186500058Q1