Karapınar, EminÖzcan, Emine2020-03-262020-03-262003Karapınar, E., Özcan, E., (2003). Synthesis of N '-[4 '-Benzo(15-crown-5)]-4-Tolylaminoglyoxime and N '-[4 '-Benzo(15-crown-5)]-4 Chlorophenylaminoglyoxime and Their Complexes With Copper (Ii), Nickel (Ii) and Cobalt (Ii). Journal of Inclusion Phenomena and Macrocyclic Chemistry, (47), 59-63. Doi: 10.1023/B:JIPH.0000003926.35770.2c1388-31271573-1111https://dx.doi.org/10.1023/B:JIPH.0000003926.35770.2chttps://hdl.handle.net/20.500.12395/18576N'-[4'-benzo(15-crown-5)]-4-tolylaminoglyoxime (H2L1), the sodium chloride salt of H2L1 (H2L1.NaCl), N'-[4'-benzo(15-crown-5)]-4-chlorophenylaminoglyoxime (H2L2) and the sodium chloride salt of H2L2 (H2L2.NaCl) have been prepared from p-chlorophenylchloroglyoxime, p-tolylchloroglyoxime, 4'-aminobenzo[15-crown-5] and sodium bicarbonate or sodium bicarbonate and sodium chloride. Nickel (II), cobalt (II) and copper (II) complexes of H2L and H2L.NaCl have a metal-ligand ratio of 1:2 and the ligand coordinates through the two N atoms, as do most of the vic-dioximes. Their IR spectra and elemental analyses are given, together with H-1 NMR spectra of the ligands.en10.1023/B:JIPH.0000003926.35770.2cinfo:eu-repo/semantics/openAccessCrown etherHlyoximesOximesTransition metal complexesArticle475963Q3WOS:000186613300009Q2