Synthesis of five new bis(amino-p-chlorophenylglyoximes) and their polymeric complexes with Ni(II), Co(II), and Cu(II)

Pekacar Ali IhsanOzcan Emine2020-03-262020-03-2619941060-1325https://hdl.handle.net/20.500.12395/16238In this study, five new bis(amino-p-chlorophenylglyoximes), 1,4-phenylene bis(amino-p-chlorophenylglyoxime); 1,1?-biphenyl-4,4?-bis(amino-p-chlorophenylglyoxime); 1,1?-diphenyloxy-4,4?-bis(amino-p-chlorophenylglyoxime); 1,1?-diphenylmethylene-4,4?-bis(amino-p-chlorophlenylglyoxime); and 1,1?-diphenylethylene-4,4?-bis(amino-p-chlorophenylglyoxime) were synthesized from anti-p-chlorophenylchloroglyoxime and the corresponding aromatic diamines. Their polymeric complexes with Ni(II), Co(II) and Cu(II) were isolated. The Ni(II) and Cu(II) complexes of these ligands are square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. 1H-NMR, AAS, IR and elemental analytical data of the complexes and ligands are discussed.eninfo:eu-repo/semantics/closedAccessSynthesis of five new bis(amino-p-chlorophenylglyoximes) and their polymeric complexes with Ni(II), Co(II), and Cu(II)ArticleA31SUPPL 5651661Q2