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    Evaluating the effectiveness of nanofillers in filament wound carbon/epoxy multiscale composite pipes
    (ELSEVIER SCI LTD, 2016) Üstün, Tugay; Ulus, Hasan; Karabulut, Salim Egemen; Eskizeybek, Volkan; Şahin, Ömer Sinan; Avcı, Ahmet; Demir, Okan
    The performance of filament wound (FW) composite pipes is considered to be fundamentally governed by fiber properties and winding angles; however, matrix dominated properties such as axial and hoop strengths are also responsible in design of FW composite pipes. This paper presents the experimental results of a project aiming to assess the benefits of addition of carbon nanotubes (CNTs) and/or boron nitride nanoplates (BNNPs) as nanofillers within epoxy matrix of FW carbon fiber composite pipes. The nanofillers enhance the burst and hoop strengths up to 17.0% and 31.7%, respectively, over the control samples. Failure analysis revealed that the morphologies of nanofillers play an important role on the matrix toughening and strengthening the fiber matrix interface. Highest mechanical performance of the multiscale composite pipes was obtained with the addition of CNTs and BNNPs within the epoxy matrix concurrently related with the synergetic effect of the two different nanofillers. (C) 2016 Elsevier Ltd. All rights reserved.
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    Low-velocity impact behavior of carbon fiber/epoxy multiscale hybrid nanocomposites reinforced with multiwalled carbon nanotubes and boron nitride nanoplates
    (SAGE PUBLICATIONS LTD, 2016) Ulus, Hasan; Ustun, Tugay; Sahin, Omer Sinan; Karabulut, Salim Egemen; Eskizeybek, Volkan; Avci, Ahmet
    In this article, the mechanical properties and dynamic response of hybrid filler-modified epoxy/carbon fiber multiscale composites were investigated. The hybrid fillers composed of multiwalled carbon nanotubes and boron nitride nanoplates were dispersed in epoxy resin and used as matrix material. The multiscale hybrid laminated composites were stacked symmetrically consisting of 10 plies of woven carbon fibers and fabricated by vacuum infusion technique. The mechanical properties of the hybrid composites were investigated by tensile tests. Impact response and energy absorption capacity were investigated by using weight drop test method and the tests were performed according to ASTM-D-7136 standard with impact energies of 5, 10, and 15J. The impact force and displacement versus interaction time were measured. The impulsive force, energy absorption capability, and damage formation were also investigated. It is observed that when the resin is modified by nanoparticles, both strength and the % strain at fracture increase considerably. However, it is shown in the subject manuscript that the enhancement of mechanical has not fully transferred to dynamic response and energy absorption capacities of nanocomposites.
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    Thermal stability and adhesive strength of boron nitride nano platelets and carbon nano tube modified adhesives
    (SAGE PUBLICATIONS LTD, 2018) Ekrem, Muersel; Sahin, Omer Sinan; Karabulut, Salim Egemen; Avci, Ahmet
    The effect of multi-walled carbon nanotube and/or boron nitride nano platelets usage on shear strength and thermal stability of epoxy based adhesives have been investigated. Commercially available diglycidyl ether of bisphenol A based epoxy was used as matrix and reinforced by using nanofillers. The resulting adhesive was tested for its shear-lap adhesion to aluminum alloy sheets (2024-T3). The nano particles modified epoxy adhesives were characterized by Fourier transform infrared, differential scanning calorimetry, and thermal gravity analyses analysis. These characterizations revealed that incorporation of nano particles can result in enhancement in chemical stability. Single lap strength joint testing was conducted in accordance with ASTM-D-1002-10 standard. Fracture morphologies and the effects of multi-walled carbon nanotubes and boron nitride nano platelets on epoxy adhesive were investigated after shear tests by means of scanning electron microscopy. Compared to neat epoxy, increases of 30% in shear strength and 57% in energy required to break joints have been obtained by multi-walled carbon nanotube/boron nitride nano platelet modification.