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Öğe Synthesis and characterization of new vic-dioximes and their metal complexes with Cu(II), Ni(II), and Co(II) salts(MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007) Coskun, A.; Koc, Z. E.4-Acetyldiphenyl sulfide and 4.4'-diacetyidiphenyl sulfide were synthesized from diphenyl sulfide and acetyl chloride in the presence of AlCl3 as catalyst in the Friedel-Crafts reaction. Subsequently, the ketooxime and glyoxime derivatives were also prepared. The metal complexes of the glyoximes, such as copper, nickel, and cobalt complexes were prepared. The BF2+ capped Ni(II) mononuclear complex of 4-thiophenoxyphenylglyoxime was prepared. The structures of these ligands were identified by FT-IR, H-1 NMR, and C-13 NMR spectral data and elemental analysis. The structures of the complexes were identified by FT-IR, elemental analysis, and magnetic measurements.Öğe Synthesis and characterization of some vic-dioxime and its mononuclear complexes(MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007) Uysal, S.; Coskun, A.; Koc, Z. E.; Ucan, M.; Ucan, H. I.In this study, acetophenone is used as a basis substance. omega-Isonitrosoacetophenone has been synthesized from nitrosyl with amyl nitrite of acetophenone in the presence of sodium ethoxide. Subsequently, anti-phenylglyoxime has been prepared by reacting omega-isonitrosoacetophenone with hydroxylamine and sodium acetate in a ethanolic media. Chlorophenylglyoxime has been obtained from reaction with chlorine gases. Then, three aminophenylglyoxime (ligands) have been prepared by the reaction of chlorophenylglyoxime and the corresponding amines. The Ni(II), Co(II), and Cu(II) complexes with BF2+-bridge of anilinophenylglyoxime and 2,4-dimethylanilinophenylglyoxime were prepared. Then polymeric metal complexes with BF2+-bridge of dopamiophenylglyoxime were prepared. Their structures were identified by FT-IR, H-1 NMR, and ICP-AES spectral data, elemental analysis and magnetic measurements.Öğe Synthesis and characterization of some vic-dioxime and its mononuclear complexes (vol 33, pg 351, 2007)(MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007) Uysal, S.; Coskun, A.; Koc, Z. E.; Ucan, M.; Ucan, H. I.[Abstract not Available]
