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    Synthesis and characterization of nickel(II) and copper(II) complexes of the Schiff bases derived from 4-/6-methyl-Delta(3)-tetrahydrobenzaldehyde and glycine
    (ASIAN JOURNAL OF CHEMISTRY, 2008) Gueler, Ersin; Ertul, Seref; Okudan, Ahmet; Kocyigit, Oezcan
    Nickel(II) and copper(II) complexes with the Schiff bases derived from 4-methyl-Delta(3)-tetrahydrobenzaldehyde or 6-methyl-Delta(3)-tetrahydrobenzaldehyde and glycine were synthesized. These compounds have been characterized by elemental analysis, conductivity measurements and infrared spectroscopy. The Schiff base ligands and their complexes have been further characterized by H-1 NMR. The results suggest that the Schiff base acts as a bidentate ligand which bonds to the metal ions through the imino nitrogen and carboxylate oxygen. The potassium salts of the Schiff bases are 1: 1 electrolytes, but all the complexes are non-electrolytes.