Yazar "Patir, Imren Hatay." seçeneğine göre listele

Listeleniyor 1 - 5 / 5
  • Küçük Resim
    Öğe
    Donor-pi-acceptor dye-sensitized photoelectrochemical and photocatalytic hydrogen evolution by using Cu2WS4 co-catalyst
    (PERGAMON-ELSEVIER SCIENCE LTD, 2019) Patir, Imren Hatay.; Aslan, Emre.; Yanalak, Gizem.; Karaman, Merve.; Sarilmaz, Adem.; Can, Mumin.; Can, Mustafa.; Ozel, Faruk.
    Photoelectrochemical and photocatalytic hydrogen evolution reaction (HER) have been investigated by using metal free donor-acceptor (D-A) and donor-pi-acceptor (D-pi-A) dyes, which are abbreviated as MC-32 and MC-048, respectively, sensitized TiO2 as a photo-catalyst with or without Cu2WS4 co-catalyst. This co-catalyst is synthesized by a low-cost and simple hot injection method, under visible light illumination. The photoactivities of these dyes have been clarified according to their structural, optical and electrochemical properties. Photocatalytic activities have been slightly increased when added the Cu2WS4 co-catalyst (dye/TiO2/Cu2WS4). This catalytic activity is also compared to that of noble metal Pt (dye/TiO2/Pt). It has been found that 121 mu molg(-1)h(-1), 179 mu molg(-1)h(-1), 348 mu molg(-1)h(-1), 212 mu molg(-1)h(-1), 422 mu molg(-1)h(-1) and 1139 mu molg(-1)h(-1) hydrogen have been evolved by using MC-32/TiO2, MC-32/TiO2/Cu2WS4, MC-32/TiO2/Pt, MC-048/TiO2, MC-048/TiO2/Cu2WS4 and MC-048/TiO2/Pt, respectively. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
  • Küçük Resim
    Öğe
    Green preparation of Carbon Quantum dots using Gingko biloba to sensitize TiO2 for the photohydrogen production
    (ELSEVIER SCI LTD, 2020) Genc, Munevver Tuna.; Yanalak, Gizem.; Arslan, Gulsin.; Patir, Imren Hatay.
    Carbon Quantum dots (CQDs) were obtained from Gingko biloba by using microwave technique, which is easy, time-saving, cost-effective, non-toxic and environmental friendly way. TiO2 were sensitized by green-prepared CQDs to obtain CQDs/TiO2 composite. The characterizations of the CQDs and CQDs/TiO2 were performed by Transmission Electron Microscopy (TEM), high-resolution TEM (HR-TEM), X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopic (XPS), Photoluminescence (PL) and Fourier Transformed Infrared (FT-IR) spectroscopy. The photocatalytic hydrogen evolution activity of CQDs/TiO2 system was studied under visible light (lambda > 420 nm) irradiation in the aqueous solution by using triethanolamine (TEOA) as a sacrificial electron donor. When Pt was used as a co-catalyst, CQDs/TiO2/Pt exhibited improved hydrogen evolution rate (1502 mu mol h(-1)g(-1)) compared to CQDs/TiO2 composite (665 mu mol h(-1)g(-1)).
  • Küçük Resim
    Öğe
    Green synthesized carbon quantum dots as TiO2 sensitizers for photocatalytic hydrogen evolution
    (PERGAMON-ELSEVIER SCIENCE LTD, 2019) Sargin, Idris.; Yanalak, Gizem.; Arslan, Gulsin.; Patir, Imren Hatay.
    Carbon quantum dots (CQDs) have attracted growing interest due to their superior luminescent properties, which make them excellent photosensitizers for TiO2. This study presents the green-synthesis of CQDs from edible mushroom Agaricus bisporus through microwave irradiation. In the study as-synthesized CQDs were used as a sensitizer for TiO2 in photocatalytic hydrogen evolution in aqueous triethanolamine (sacrificial reagent) under visible-light irradiation. Photocatalytic hydrogen production activity of CQD-sensitized TiO2 was found to be 472 mu mol g(-1) h(-1) (without loading any noble metal co-catalyst) and 1458 mu mol g(-1) h(-1) (with loading Pt co-catalyst). The study revealed that the CQDs from mushroom A. bisporus can be used as an efficient sensitizer for TiO2 in photocatalytic hydrogen production. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
  • Küçük Resim
    Öğe
    The investigation of novel D-pi-A type dyes (MK-3 and MK-4) for visible light driven photochemical hydrogen evolution
    (ELSEVIER SCI LTD, 2019) Aslan, Emre.; Karaman, Merve.; Yanalak, Gizem.; Can, Mustafa.; Ozel, Faruk.; Patir, Imren Hatay.
    Two novel donor-n-acceptor (D-pi-A) semiconductor organic dyes have been synthesized for the photochemical hydrogen evolution reaction (HER) to sensitize TiO2 for the first time. The molecular structures of D-pi-A semiconductor organic dyes, which are entitled as MK-3 and MK-4, have been characterized by NMR spectroscopy method; and also electrochemical and optical properties have been investigated by cyclic voltammetry and UV-Vis absorption techniques, respectively. Amount of dye loading on TiO2 surface has been investigated by EDX method. The HER activities have been explored in the presence of triethanolamine (TEOA) as a electron donor reagent under sunlight (solar simulator illumination limited by cut-off filter lambda >= 420 nm) in the absence and presence of co-catalysts (Pt and Cu2WS4). Transient photocurrent densities of MK-3/TiO2 and MK-4/TiO2 electrodes have been reached to 110 mu A cm(-1) and 275 mu A cm(-1), respectively. The photocatalytic HER activities have been relatively enhanced in the presence of the Pt or Cu2WS4 co-catalysts (dye/TiO2/Cu2WS4 or dye/TiO2/Pt) when compared to only dye/TiO2. The HER rates have been found as 427, 1277, 675, 682, 1027 and 795 mu molg(-1) h(-1) for the MK-3/TiO2, MK-3/TiO2 /Pt, MK-3/TiO2/Cu2WS4, MK-4/TiO2, MK-4/TiO2/Pt and MK4/TiO2/Cu2WS4 , respectively. The differences of photochemical activities of MK-3/TiO2 and MK-4/TiO2 have been stated taking into account dye molecule structures. Moreover, the HER mechanism have been described by using electrochemical band energy levels of dyes, TiO2 and Cu2WS4 co-catalyst.
  • Küçük Resim
    Öğe
    Synthesis of novel tetrazine based D-pi-A organic dyes for photoelectrochemical and photocatalytic hydrogen evolution
    (ELSEVIER SCIENCE SA, 2020) Aslan, Emre.; Karaman, Merve.; Yanalak, Gizem.; Bilgili, Hakan.; Can, Mustafa.; Ozel, Faruk.; Patir, Imren Hatay.
    Two novel donor-pi-acceptor (D-pi-A) dyes, called as MK-2 and MK-8, are synthesized. Their structural, optical and electrochemical properties are investigated by NMR, absorption/photoluminescence spectroscopies and cyclic voltammetry techniques, respectively. Photocatalytic and photoelectrochemical hydrogen evolution properties of these D-pi-A dyes are explored by using triethanolamine (TEOA) as a sacrificial electron donor under anaerobic conditions and visible light irradiation with or without co-catalysts (Cu2WS4 and Pt) for the first time. Photoelectrochemical and photocatalytic hydrogen evolution reaction (HER) activities of these dyes are studied by using TiO2 coated FTO electrodes and powdered TiO2 (Degussa P25), respectively. Photoelectrochemical response of MK-2/TiO2 and MK-8/TiO2 are figured out in the order of 180 mu A cm(-1) and 80 A cm(-1). The photocatalytic hydrogen evolution amounts of MK-2/TiO2, MK-2/TiO2/Cu2WS4, MK-2/TiO2/Pt, MK-8/TiO2, MK-8/TiO2/Cu2WS4 and MK-8/TiO2/Pt are turned out to be 565, 920, 1828, 374, 522 and 1260 mu molg(-1) h(-1), respectively. Dye/TiO2 photocatalysts are displayed good stability in the both photochemical HER experiments. The alteration in the HER activities of MK-2 and MK-8 is explained by molecule structures of dyes. The proposed mechanism of photocatalytic hydrogen evolution is clarified by using electrochemical band levels of each constituent.