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Öğe Adsorption of ferrocyanide onto raw and acid-activated clinoptilolite and sepiolite: equilibrium modelling by error minimization(MINERALOGICAL SOC, 2013) Onen, V.; Yel, E.The experimental data on adsorption of Fe and CN of a ferrocyanide complex onto raw and acid-activated clinoptilolite/sepiolite on the basis of detention time and particle size was modelled by a linear and a non-linear approach. The linearized best-fit isotherm selection method and non-linear error minimization was applied through Freundlich, Langmuir and Temkin isotherms. ERRSQ, MPSD, HYBRID and ARE error functions were minimized by a developed MATLAB script to determine the isotherm parameters in non-linear optimization. The complex was not adsorbed as whole anions but the Fe and CN were adsorbed separately. 0.65 mg Fe/L.min and 4.84 mg CN/L.min initial adsorption rates were achieved with acid activated clinoptilolite. The Fe adsorption was not as successful as CN. The adsorption of Fe and CN was described by Freundlich and Langmuir isotherms respectively. The differences between the predicted isotherm parameter sets of linear models and minimized error function models indicated that both the best-fit isotherm selection and the isotherm constant determinations can be performed properly by error minimization as well as by conventional linear best fit modelling approach.Öğe The comparison of THMs and HAAs formation and speciation by chlorination and chloramination for different water sources(GLOBAL NETWORK ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2017) Kucukcongar, S.; Sevimli, M. F.; Yel, E.Disinfection by-products (DBPs) can be controlled by using alternative disinfectants to chlorine, removing DBPs precursors prior to chlorination and removing DBPs after formed. Chloramine is widely used as an alternative disinfectant to chlorine usage. In this study to evaluate trihalomethanes (THMs) and haloacetic acids (HAAs) formation and speciation for Altinapa and Omerli dam water isolates after chlorination and choramination procedures at different pH values was aimed. Compared with chlorination, the formation of THMs was reduced by approximately 4-fold in chloramination for Omerli dam water. Total THM concentrations remained below detection limits in Altinapa isolate after chloramination. The dominant species were CF and followed by BDCM and CDBM in case of chlorination, and almost no BF formed. BF is the dominant specie together with CF in case of chloramination, and no BDCM and CDBM formed at all pHs for Omerli dam water. HAA concentrations resulting from the use of chlorine were obtained 4.8-5.1 times higher from resulting from the use of chloramines at different pH values for Omerli Dam water; but this value was 5.5-8.7 for Altinapa Dam water. MCAA, DCAA and BCAA concentrations were a large part of the total HAA concentrations which obtained from chloramines usage for both isolates.Öğe DBP FORMATION AND SPECIATION IN A CENTRAL ANATOLIAN DAM WATER DEPENDING ON pH, TOC LEVEL, FRACTION AND CHLORINE DOSE(GLOBAL NETWORK ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2013) Kucukcongar, S.; Sevimli, M. F.; Yel, E.The effects of pH, NOM concentration, fractions and the chlorine dose on the formation and speciation of THMs and HAAs were determined in Altinapa Dam water (Konya/Turkey). Water sample was isolated and chlorinated at different TOC levels and pH's. The isolate was fractioned; THM and HAA species were measured after chlorination. THM increased with increasing pH (6 to 8) whereas a consistent pH tendency could not be inferred from the HAA changes. CF is the dominant THM specie which exerts up to 91% of the total THM. The majority of total HAAs composed of MCAA, DCAA and TCAA. The hydrophobic fraction was the main THM precursor under the studied conditions although their percentage was lower than hydrophilics, whereas, hydrophilic fraction had significant contribution to HAA formation, in contrast to the general tendency for HAA. High correlation (0.97) was calculated between total THMs and HAAs.Öğe Investigation of Pb(II) Adsorption Onto Natural and Synthetic Polymers(Wiley, 2012) Ahmetli, Gülnare; Yel, E.; Deveci, H.; Bravo, Z.; Bravo, Y.Adsorption of toxic metal ion Pb(II) onto two different insoluble humic acids (IHAs) obtained from Beysehir (BIHA) and Ermenek (EIHA) low grade lignites and two synthesized terpolymers: styrene-divinylbenzene-methacrylic acid (SDBM) and styrene-divinylbenzene allylmethacrylate (SDBAM) were investigated and compared with commercial activated carbon (AC). The synthesized polymers were characterized by FTIR. Effects of pH (in neutral and acidic range), time, and initial metal concentration on the effectiveness of IHAs and terpolymers were determined. All synthesized adsorbents could adsorb Pb(II) with much higher capacity at half of the retention of AC in acidic medium. The adsorption capacities varied in the range of 5176 mg g-1. The affinity order of polymers in acidic medium for Pb(II) ions was observed as: SDBAM>SDBM>BIHAEIHA>AC. IHAs fit Freundlich model while SDB polymers were fitting Langmuir isotherm. The maximum adsorption capacities in neutral medium were 48 mg g-1 for SDBM and 15 mg g-1 for BIHA. Desorption studies for the polymer of highest performance indicated that about 90% desorption was achieved at 5 h by using EDTA regenerant solution. The polymer can be used repeatedly in Pb(II) adsorption with close capacities to initial use. The higher selectivity of SDBAM to Pb(II) ions in multimetal solution was also indicated in the study.
