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Öğe The Synthesis of Four New Schiff Bases and Some of Their Transition Metal Complexes(MARCEL DEKKER INC, 1998) Uçan, H. I.; Karataş, I.; Irez, G.; Deveci, M. A.; Mercimek, B.Isonitrosoacetophenone, synthesized by nitrosotion of acetophenone, has been condensed with diamines (1,4-phenylenediamine, 4,4'-diaminobiphenyl, 4,4'-diaminodiphenylmethane or 4,4'-diaminodiphenylether) to obtain the tetradentate Schiff bases 1,4-phenyliminobis(isonitrosoacetophenone), 1,1'-biphenyl-4,4'-diiminobis(isonitrosoacetophenone), 1,1'-diphenylmethane-4,4'-diiminobis(isonitrosoacetophenone) or 1,1'-diphenyloxy-4,4'-diiminobis(isonitrosoacetophenone). The polymeric Ni(II) and Cu(II) complexes of these Schiff bases are square-planar while the polymeric Co(II) complexes are octahedral with water molecules at the axial positions. The structures of the above complexes were determined by H-1 NMR and IR spectroscopy and elemental analyses.Öğe Synthesis of iminooxime derivatives and investigation of their complexes(MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007) Sahin, M.; Kocak, N.; Ucan, H. I.; Deveci, M. A.Three novel ligands, a-pycolyliminoisonitrosoacetophenone ((LH)-H-1 center dot HCl), alpha-pycolylimino-p-methylisonitrosoacetophenone ((LH)-H-2 center dot HCl), and a-pycolylimino-p-chloroisonitrosoacetophenone (LH)-H-3, were synthesized. Their metal complexes with Co(II), Cu(II), and Ni(II) were prepared. The mononuclear complexes of these ligands with Co2+, Cu2+, and Ni2+ ions were obtained in ethanol. The structures of the ligands and their complexes were characterized by 1H NMR, IR spectroscopy, elemental analyses, and magnetic susceptibility.