The Synthesis of Four New Schiff Bases and Some of Their Transition Metal Complexes

Küçük Resim Yok

Tarih

1998

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

MARCEL DEKKER INC

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Isonitrosoacetophenone, synthesized by nitrosotion of acetophenone, has been condensed with diamines (1,4-phenylenediamine, 4,4'-diaminobiphenyl, 4,4'-diaminodiphenylmethane or 4,4'-diaminodiphenylether) to obtain the tetradentate Schiff bases 1,4-phenyliminobis(isonitrosoacetophenone), 1,1'-biphenyl-4,4'-diiminobis(isonitrosoacetophenone), 1,1'-diphenylmethane-4,4'-diiminobis(isonitrosoacetophenone) or 1,1'-diphenyloxy-4,4'-diiminobis(isonitrosoacetophenone). The polymeric Ni(II) and Cu(II) complexes of these Schiff bases are square-planar while the polymeric Co(II) complexes are octahedral with water molecules at the axial positions. The structures of the above complexes were determined by H-1 NMR and IR spectroscopy and elemental analyses.

Açıklama

Anahtar Kelimeler

Kaynak

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

WoS Q Değeri

Q4

Scopus Q Değeri

N/A

Cilt

28

Sayı

3

Künye

Uçan, H. I., Karataş, I., Irez, G., Deveci, M. A., Mercimek, B., (1998). The Synthesis of Four New Schiff Bases and Some of Their Transition Metal Complexes. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 28(3), 331-338.