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Öğe The Aliphatic Bis(Aminoglyoximes), Preparation of Their Geometric Isomers and Structural Investigation of Their Ni(Ii), Co(Ii) and Cu(Ii) Complexes(MARCEL DEKKER INC, 1995) Deveci,M. Ali; Irez, GaziThis investigation describes the synthesis of amphi- and anti-isomers of 1,2-bis(aminoglyoxime)ethane dihydrochloride (EGBH(2).2HCl) and amphi-isomers of 1,3-bis(aminoglyoxime)propane dihydrochloride (PBGH(2).2HCl). The preparation of NI(II), Co(II) and Cu(II) complexes of the amphi- and anti-isomers of these ligands are described. All these complexes are insoluble in common solvents. Structures are proposed based on elemental analyses, IR, and magnetic susceptibility measurements.Öğe The Synthesis and Ni(Ii), Co(Ii) and Cu(Ii) Complexes of Three New Unsymmetrical Vic-Dioximes(MARCEL DEKKER INC, 1995) Deveci, M. All; Irez, Gazi; Mercimek, Bedrettin; Bedük, A. Dinçer; Sarıkavaklı, NursabahThe reaction of anti-chlorophenylglyoxime with suitable alkylamines in ethanol-water at 0 degrees C gives the unsymmetrical vic-dioximes, namely, N-ethylaminophenylglyoxime (L(1)H(2)), N-propylaminoglyoxime (L(2)H(2)) and N-butylaminoglyoxime (L(3)H(2)). The Ni(li) and Cu(II) complexes of these ligands are square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. The structures of these complexes are proposed based on elemental analyses, IR and magnetic susceptibility measurements.