Synthesis, structure, spectroscopic studies and ab-initio calculations on first hyperpolarizabilities of N,N'-bis(2-hydroxy-1-naphthyl-methylidene)-1- methyl-1,2-diaminoethane-N,N',O,O'-copper(II)

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dc.contributor.authorKarakaş A.
dc.contributor.authorElmali A.
dc.contributor.authorÜnver H.
dc.contributor.authorKara H.
dc.contributor.authorYahsi Y.
dc.date.accessioned2020-03-26T17:05:36Z
dc.date.available2020-03-26T17:05:36Z
dc.date.issued2006
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractN,N'-Bis(2-hydroxy-1-naphthylmethylidene)-1-methyl-1,2-diaminoethane-N,N', O,O'-copper(II) has been synthesized, and characterized by FT-IR and UV/vis spectroscopies. Its crystal structure has been determined by X-ray diffraction analysis. The maximum absorption wavelengths recorded by linear optical experiments are estimated in the UV region to be shorter than 450 nm, showing good optical transparency to the visible light. It may thus possess first hyperpolarizabilities with non-zero values for nonlinear optical (NLO) applications. Ab-initio quantum chemical calculations of the electric dipole moments (?) and the first static hyperpolarizabilities (?) were carried out. The computational results suggest that the complex may indeed have microscopic NLO behavior with non-zero values. © 2006 Verlag der Zeitschrift für Naturforschung.en_US
dc.description.sponsorshipCHE 2003 00 00 041 Balikesir Ãœniversitesi: 2003/20 2003/ 030 105T132en_US
dc.description.sponsorshipThe authors would like to thank TUBITAK (105T132), Research Funds of Ankara University (CHE 2003 00 00 041), Balikesir University (2003/20), and Selc¸uk University (2003/ 030) for financial support. Hulya Kara also thanks the Nato-B1-TUBITAK for funding and Prof. Guy Orpen (School of Chemistry, University of Bristol, UK) for his hospitality.en_US
dc.identifier.doi10.1515/znb-2006-0807en_US
dc.identifier.endpage974en_US
dc.identifier.issn0932-0776en_US
dc.identifier.issue8en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage968en_US
dc.identifier.urihttps://dx.doi.org/10.1515/znb-2006-0807
dc.identifier.urihttps://hdl.handle.net/20.500.12395/20933
dc.identifier.volume61en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherVerlag der Zeitschrift fur Naturforschungen_US
dc.relation.ispartofZeitschrift fur Naturforschung - Section B Journal of Chemical Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCopper(II) Complexen_US
dc.subjectCrystal Structureen_US
dc.subjectElectric Dipole Momenten_US
dc.subjectFirst Hyperpolarizabilityen_US
dc.subjectUV-visible Spectroscopyen_US
dc.titleSynthesis, structure, spectroscopic studies and ab-initio calculations on first hyperpolarizabilities of N,N'-bis(2-hydroxy-1-naphthyl-methylidene)-1- methyl-1,2-diaminoethane-N,N',O,O'-copper(II)en_US
dc.typeArticleen_US

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