Third-order nonlinear optical properties of copper(II)bis{2-[(4-iodophenyl)iminomethyl]-6-methoxy-phenolate}
| dc.contributor.author | Yaglioglu, Halime G. | |
| dc.contributor.author | Karakas, Asli | |
| dc.contributor.author | Unver, Hseyin | |
| dc.contributor.author | Elmali, Ayhan | |
| dc.date.accessioned | 2020-03-26T17:04:41Z | |
| dc.date.available | 2020-03-26T17:04:41Z | |
| dc.date.issued | 2006 | |
| dc.department | Selçuk Üniversitesi | en_US |
| dc.description.abstract | Copper(II)bis {2-[(4-iodophenyl)iminomethyl]-6-methoxy-phenolate} has been synthesized, characterized by UV-visible spectroscopy, and its crystal structure determined by X-ray diffraction. The Cu atom is situated on a twofold axis and the geometry around the metal centre can be described as distorted square planar with a trans configuration. The absorption maxima are shorter than 450 nm, giving rise to good optical transparency in the visible and near IR. To reveal the microscopic third-order NLO properties, the static second hypetpolarizabilities have been evaluated by using the ab initio time-dependent Hartree-Fock (TDHF) method. According to the results, the title complex exhibits non-zero gamma values, implying microscopic third-order NLO behavior. | en_US |
| dc.identifier.endpage | 1360 | en_US |
| dc.identifier.issn | 0932-0776 | en_US |
| dc.identifier.issue | 11 | en_US |
| dc.identifier.startpage | 1355 | en_US |
| dc.identifier.uri | https://hdl.handle.net/20.500.12395/20752 | |
| dc.identifier.volume | 61 | en_US |
| dc.identifier.wos | WOS:000243369900007 | en_US |
| dc.identifier.wosquality | Q3 | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | VERLAG Z NATURFORSCH | en_US |
| dc.relation.ispartof | ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.selcuk | 20240510_oaig | en_US |
| dc.subject | copper(II) complex | en_US |
| dc.subject | time-dependent Hartree-Fock | en_US |
| dc.subject | static third-order hyperpolarizability | en_US |
| dc.subject | UV-visible spectroscopy | en_US |
| dc.subject | ab initio calculation | en_US |
| dc.title | Third-order nonlinear optical properties of copper(II)bis{2-[(4-iodophenyl)iminomethyl]-6-methoxy-phenolate} | en_US |
| dc.type | Article | en_US |
