Reduced transport numbers of PolysulfoneMembranes from the initial time EMF measurements
Küçük Resim Yok
Tarih
2012
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Initial membrane potentials of polysulfone cation exchange membranes were measured with KCl, NaCl, LiCl CaCl 2 and FeCl 3 solutions by using Ag/AgCl electrodes. The measurements were carried out for KCl / unsupported polysulfone cation exchange membranes (SA 3S) or polyester supported polysulfone cation exchange membranes (SA 3T) / KCl, NaCI, LiCI, CaCl 2 and FeCl 3 systems. The concentration of KCl, C 1, was kept constant at 1.10 -2 M in one cell; however the concentrations of KCl, NaCI, LiCl, CaCl 2 and FeCl 3, C 2, in the other cell were changed from 1.10 -4 M to 2.0 M. The Supported face of SA 3T membrane was brought to equilubrium with the left- hand solution and then, the unsupported face of SA 3T membrane was exposed to the right-hand solution. Transport number of K +, Na +, Li +, Ca +2, Fe +3 ions corresponding to the each of two surface layers of the membrane was evaluated from the initial time and the fifth minute emf measurements. The results were compared with between unsupported polysulfone cation exchange membranes and polyester supported polysulfone cation exchange membranes.
Açıklama
Anahtar Kelimeler
? mean, Cation exchange membrane, Initial time, The mean reduced transport number
Kaynak
Gazi University Journal of Science
WoS Q Değeri
Scopus Q Değeri
Q3
Cilt
25
Sayı
3
