Tereftalaldoksimin bazı kompleksleri ve polimerlerinin sentezi
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Dosyalar
Tarih
2002
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Selçuk Üniversitesi, Fen Bilimleri Enstitüsü
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Bu çalışmada tereftalaldehitin bazik ortamda hidroksilamin hidroklorür ile kondenzasyon reaksiyonundan tereftaldoksim elde edildi. Daha sonra tereftaldoksimin dioksan veya CCl4 çözeltisi içerisinden klor gazı geçirilerek tereftalohidroksamoil klorür elde edildi. Tereftalohidroksimoil klorürün bazı özel primer aminler ile reaksiyonları yapıldı. Elde edilen Tereftalo-N,N'-di-2-furfuril amidoksim ve Tereftalo-N,N'-di-(2-piridilmetil) amidoksimin Ni(II), Cu(II) ve Co(II) kompleksleri izole edildi. Tereftalohidroksimoil klorürün 2-amino-4-metil fenol ile reaksiyonundan ise halka kapanması sonucu benzoksazol türevi elde edildi. Bileşiklerin yapıları Elemental Analiz, FT-IR, 1H-NMR ve ICP-AES teknikleriyle aydınlatılmaya çalışıldı.
In this study terephthalaldoxime was obtained from the condensation reaction of terephthalaldehyde with hydroxylammonium chloride in basic medium. After that terephthalohydroxamoyl chloride was obtained by passing Cl2 gas through dioxane or CCl4 solutions of terephthalaldoxime. The reactions of terephthalohydroxamoyl chloride were performed with some private primer amines. Ni(II), Cu(II) and Co(II) complexes of terephthalo-N,N'-di-2-furfuryl amidoxime and terephthalo-N,N'-di-(2-pyridylmethyl) amidoxime were isoleted. After the reaction of terephthalohydroxamoyl chloride with 2-amino-4-methyl phenol , banzoxazole darivate was obtained as a result of ring closing. The structures of these compounds were analyzed by using Elementary Analyses, FT-IR, 1H-NMR and ICP-AES techniques.
In this study terephthalaldoxime was obtained from the condensation reaction of terephthalaldehyde with hydroxylammonium chloride in basic medium. After that terephthalohydroxamoyl chloride was obtained by passing Cl2 gas through dioxane or CCl4 solutions of terephthalaldoxime. The reactions of terephthalohydroxamoyl chloride were performed with some private primer amines. Ni(II), Cu(II) and Co(II) complexes of terephthalo-N,N'-di-2-furfuryl amidoxime and terephthalo-N,N'-di-(2-pyridylmethyl) amidoxime were isoleted. After the reaction of terephthalohydroxamoyl chloride with 2-amino-4-methyl phenol , banzoxazole darivate was obtained as a result of ring closing. The structures of these compounds were analyzed by using Elementary Analyses, FT-IR, 1H-NMR and ICP-AES techniques.
Açıklama
Anahtar Kelimeler
Tereftaldoksim, Terefatlohidroksamoil Klorür, Amidoksim, Terephthalaldoxime, Terephthalohydroxmoyl Cgloride, Amidoxime
Kaynak
WoS Q Değeri
Scopus Q Değeri
Cilt
Sayı
Künye
Özaytekin, İ. (2002). Tereftalaldoksimin bazı kompleksleri ve polimerlerinin sentezi. (Yüksek Lisans Tezi). Selçuk Üniversitesi, Fen Bilimleri Enstitüsü, Konya.
