Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb2+ Transfer across Water/1,2-Dichloroethane Interface

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dc.contributor.authorBaslak, Canan
dc.contributor.authorBingol, Haluk
dc.contributor.authorCoskun, Ahmet
dc.contributor.authorAtalay, Tevfik
dc.date.accessioned2020-03-26T18:16:26Z
dc.date.available2020-03-26T18:16:26Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe transfer of Pb2+ facilitated by interfacial complexation with 5-(4-phenoxyphenyl)-6H-1,3,4-thiadiazin-2-amine (PPTA) at the polarized water/1,2-dicholoroethane (1,2-DCE) interface was investigated by cyclic voltammetry. We synthesized the thiadiazine derivative, PPTA, firstly. The transfer was performed at different metal concentrations and scan rates, and the obtained voltammetric transfer peaks toward Pb2+ ion over other divalent cations (Zn2+, Co2+, Ni2+, Cd2+, Hg2+, and Cu2+) were reversible. The dependence of the half-wave potentials of the Pb2+ ion on the concentration of PPTA in the organic phase indicates that the ion transfer is facilitated by the formation of 1:2 (metal: ligand) complex in the organic phase with the association constant (Ig beta(2)) of (17.1 +/- 0.2).en_US
dc.description.sponsorshipSelcuk University, TurkeySelcuk University [BAP-07201027]en_US
dc.description.sponsorshipThe project was supported by the Scientific Research Fund of Selcuk University, Turkey (BAP-07201027).en_US
dc.identifier.doi10.3866/PKU.WHXB20110801en_US
dc.identifier.endpage1862en_US
dc.identifier.issn1000-6818en_US
dc.identifier.issue8en_US
dc.identifier.startpage1859en_US
dc.identifier.urihttps://dx.doi.org/10.3866/PKU.WHXB20110801
dc.identifier.urihttps://hdl.handle.net/20.500.12395/26868
dc.identifier.volume27en_US
dc.identifier.wosWOS:000292877400011en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherPEKING UNIV PRESSen_US
dc.relation.ispartofACTA PHYSICO-CHIMICA SINICAen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectPb2+en_US
dc.subjectThiadiazineen_US
dc.subjectCyclic voltammetryen_US
dc.subjectIon transferen_US
dc.subjectITIESen_US
dc.titleSynthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb2+ Transfer across Water/1,2-Dichloroethane Interfaceen_US
dc.typeArticleen_US

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