Porphyrin-Bodipy combination: synthesis, characterization and antenna effect
Küçük Resim Yok
Tarih
2014
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
ROYAL SOC CHEMISTRY
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
This paper described the synthesis of multichromophoric and pi-conjugated macromolecules consisting of two equal Bodipy units and one porphyrin unit (free base). Then, a zinc(II) complex of this macromolecule based on Bodipy and porphyrin was prepared by a classical complex reaction. The formation of nitroporphyrin, aminoporphyrin, Bodipy-porphyrin (PB) and Bodipy-metalloporphyrin (Zn-PB) was confirmed by H-1-NMR, C-13-NMR, elemental analysis, UV-vis/fluorescence spectra, melting point and ESI-TOF-MS techniques. Moreover, the photophysical properties of chromophoric groups such as absorption, emission and quantum yields were investigated for the photoinduced energy transfer in three different organic solvents. The result indicated that the emission of Bodipy in the Bodipy-porphyrin combination was significantly quenched with the formation of the free base and zinc(II) complex of porphyrin. Efficient energy transfer from the Bodipy unit to the porphyrins (free base or Zn-chelate) was observed between 88% and 96% due to high pi-conjugation. The energy transfer also occurred from Bodipy to porphyrin though the high polarity of acetonitrile.
Açıklama
Anahtar Kelimeler
Kaynak
RSC ADVANCES
WoS Q Değeri
Q1
Scopus Q Değeri
Cilt
4
Sayı
88
