2,3-furandion'ların çeşitli nükleofillerle bazı yeni reaksiyonlarının araştırılması
Yükleniyor...
Dosyalar
Tarih
2011-01-12
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Selçuk Üniversitesi Fen Bilimleri Enstitüsü
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Bu çalışmada sırasıyla N- nükleofiller ve çeşitli karbonillerle yeni bisiklik oksalil bileşiği olan 4-benzoil-5 fenil-2,3-furandionun nükleofilik ve siklokatılma reaksiyonları araştırıldı. Sonuç olarak sırasıyla 4-Benzoil-1-(2-florfenil)-5-fenil-1H-pirazol-3-karboksilikasit (AE-1), 4-Benzoil-1-(4-florfenil)-5-fenil-1H-pirazol-3-karboksilikasit (AE-2), 4-Benzoil-1-(2-florfenil)-5-fenil-1H-pirazol-3-karbonil klorür (AE-3), 4-Benzoil-1-(2-florfenil)-5-fenil-1H-pirazol-3-karboksiamid (AE-4), 4-Benzoil-1-(2-florfenil)-5-fenil-1H-pirazol-3-karboksilik metil esteri (AE-5), 4-Benzoil-1-(2-florfenil)-5-fenil-1H-pirazol-3-karboksilik propil esteri (AE-6), 2-(2-Florfenil)-6-(2-nitrofenil)-3,4-difenil-2H-pirazol[3,4-d]piridazin-7(6H)-on (AE-7), 2-(2-Florfenil)-6-(3-nitrofenil)-3,4-difenil-2H-pirazol[3,4-d]piridazin-7(6H)-on (AE-8), Benzaldehit-2-florfenil hidrazonu (AE-9) heterosiklik bileşiklerinin izolesi gerçekleştirildi. Bu bileşiklerin yapıları IR, 13C-NMR, 19F-NMR ve 1H-NMR spektrumları ile aydınlatıldı.
In this study, 4-benzoyl–5 Phenyl–2,3-furandion‟s which is a new bicyclic compound of N-nucleophiles and various carbonyl oksalil, nucleophilic and cyclo-addition reactions were investigated. As a result, respectively, isolation of heterocyclic compounds of 4-Benzoyl-1-(2-florphenyl)-5-phenyl-1H-pyrazole-3-carboxylicacid (AE-1), 4-Benzoyl-1-(4-florphenyl)-5-phenyl-1H-pyrazole-3-carboxylicacid (AE-2), 4-Benzoyl-1-(2-florphenyl)-5-phenyl-1H-pyrazole-3-carbonyl chloride (AE-3), 4-Benzoyl-1-(2-florphenyl)-5-phenyl-1H-pyrazole-3-carboxamide (AE-4), Methyl 4-Benzoyl-1-(2-florphenyl)-5-phenyl-1H-pyrazole-3-carboxylate (AE-5), Propyl 4-Benzoyl-1-(2-Florphenyl)-5-phenyl-1H-pyrazole-3-carboxylate (AE-6), 2-(2-Florphenyl)-6-(2-nitrophenyl)-3,4-diphenyl-2H-pyrazolo[3,4-d]pyridazin-7(6H)-one (AE-7), 2-(2-Florphenyl)-6-(3-nitrophenyl)-3,4-diphenyl-2H-pyrazolo[3,4-d]pyridazin-7(6H)-one (AE-8), Benzaldehyde-2-florphenyl hydrazone (AE-9) were taken placed. The structure of these compounds were revealed by IR, 13C-NMR, 19F-NMR ve 1H-NMR spectrums.
In this study, 4-benzoyl–5 Phenyl–2,3-furandion‟s which is a new bicyclic compound of N-nucleophiles and various carbonyl oksalil, nucleophilic and cyclo-addition reactions were investigated. As a result, respectively, isolation of heterocyclic compounds of 4-Benzoyl-1-(2-florphenyl)-5-phenyl-1H-pyrazole-3-carboxylicacid (AE-1), 4-Benzoyl-1-(4-florphenyl)-5-phenyl-1H-pyrazole-3-carboxylicacid (AE-2), 4-Benzoyl-1-(2-florphenyl)-5-phenyl-1H-pyrazole-3-carbonyl chloride (AE-3), 4-Benzoyl-1-(2-florphenyl)-5-phenyl-1H-pyrazole-3-carboxamide (AE-4), Methyl 4-Benzoyl-1-(2-florphenyl)-5-phenyl-1H-pyrazole-3-carboxylate (AE-5), Propyl 4-Benzoyl-1-(2-Florphenyl)-5-phenyl-1H-pyrazole-3-carboxylate (AE-6), 2-(2-Florphenyl)-6-(2-nitrophenyl)-3,4-diphenyl-2H-pyrazolo[3,4-d]pyridazin-7(6H)-one (AE-7), 2-(2-Florphenyl)-6-(3-nitrophenyl)-3,4-diphenyl-2H-pyrazolo[3,4-d]pyridazin-7(6H)-one (AE-8), Benzaldehyde-2-florphenyl hydrazone (AE-9) were taken placed. The structure of these compounds were revealed by IR, 13C-NMR, 19F-NMR ve 1H-NMR spectrums.
Açıklama
Anahtar Kelimeler
4-Benzoil, 5-fenil-2, 3-furandion, Nükleofilik katılma, Pirazol, Piridazin, 4-Benzoyl, 5-phenyl-2, Nucleophilic addition, Pyrazole, Pyridazine
Kaynak
WoS Q Değeri
Scopus Q Değeri
Cilt
Sayı
Künye
Erdem, A. (2011). 2,3-furandion'ların çeşitli nükleofillerle bazı yeni reaksiyonlarının araştırılması.Yayımlanmış yüksek lisans tezi, Selçuk Üniversitesi, Konya.
