Mathematical modeling of vapor sorption in pyrene-labelled polystyrene LB thin film studied by surface plasmon resonance spectroscopy
Yükleniyor...
Dosyalar
Tarih
2012
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Selcuk University Research Center of Applied Mathematics
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Sorption process by surface plasmon resonance (SPR) was studied by exposing polymeric film coated with pyrene-labeled polystyrene (PS) chains to various concentrations of saturated chloroform vapor. It was observed that the reflectivity changes were fast and reversible. The changes in reflectivity implied the swelling behavior of polymeric film during adsorbtionand can be explained by capturing of chloroform molecules.Fick's law for diffusion was used to quantify real time SPR data for the swelling proces. It was observed that diffusion coefficients (D_{s}) for swelling obeyed the t1/2 law and found to be correlated with the amount of chloroform content in the cell.
Açıklama
URL: http://sjam.selcuk.edu.tr/sjam/article/view/321
Anahtar Kelimeler
Langmuir-Blodgett thin films, Polystyrene, Diffusion coefficient, Langmuir-Blodgett ince filmler, Difüzyon katsayısı, Polisitren
Kaynak
Selcuk Journal of Applied Mathematics
WoS Q Değeri
Scopus Q Değeri
Cilt
13
Sayı
Künye
Özbek, Z. (2012). Mathematical modeling of vapor sorption in pyrene-labelled polystyrene LB thin film studied by surface plasmon resonance spectroscopy. Selcuk Journal of Applied Mathematics, 13 (1), 111-123.
