A hydrogen ion-selective poly (vinyl chloride mebrane electrode based on calix (4)arene as a perchlorate ion-selective electrode
dc.contributor.author | Canel, Esin | |
dc.contributor.author | Erden, Sevcan | |
dc.contributor.author | Özel, Demirel Ayça | |
dc.contributor.author | Memon, Sahahabuddin | |
dc.contributor.author | Yılmaz, Mustafa | |
dc.contributor.author | Kılıç, Esma | |
dc.date.accessioned | 2020-03-26T17:26:14Z | |
dc.date.available | 2020-03-26T17:26:14Z | |
dc.date.issued | 2008 | |
dc.department | Selçuk Üniversitesi | en_US |
dc.description.abstract | A hydrogen ion-selective electrode was prepared using 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetracya-nometoxy-calix[4]arene and the possibility of its use as a perchlorate ion-selective electrode was investigated using its characteristic of becoming perchlorate sensitive in acidic regions. The electrode of the optimum characteristic had a composition of 1% ionophore, 66% o-NPOE, and 33% PVC. This electrode exhibited a linear response over the range 1.0 x 10{-1}-1.0 x 10{-5} M of perchlorate with a slope of 48.7. ± 0.5- mV per p[Cl04]. The effects of the pH and the membrane composition were also investigated. The lifetime of the electrode was at least 4 months and its response time was 10-15 s. The selectivity coefficients of some anions were calculated by the matched potential method. | en_US |
dc.identifier.endpage | 332 | en_US |
dc.identifier.issn | 1300-0527 | en_US |
dc.identifier.issn | 1303-6130 | en_US |
dc.identifier.issue | 3 | en_US |
dc.identifier.startpage | 323 | en_US |
dc.identifier.uri | http://www.trdizin.gov.tr/publication/paper/detail/Tnpjd05ERXg= | |
dc.identifier.uri | https://hdl.handle.net/20.500.12395/22087 | |
dc.identifier.volume | 32 | en_US |
dc.indekslendigikaynak | TR-Dizin | en_US |
dc.language.iso | en | en_US |
dc.relation.ispartof | Turkish Journal of Chemistry | en_US |
dc.relation.publicationcategory | Makale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.selcuk | 20240510_oaig | en_US |
dc.subject | Mühendislik | en_US |
dc.subject | Kimya | en_US |
dc.title | A hydrogen ion-selective poly (vinyl chloride mebrane electrode based on calix (4)arene as a perchlorate ion-selective electrode | en_US |
dc.type | Article | en_US |