Synthesis of norbornadiene-containing polyamide based polymer
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Date
2016
Journal Title
Journal ISSN
Volume Title
Publisher
Chemical Publishing Co.
Access Rights
info:eu-repo/semantics/openAccess
Abstract
Synthesis of polyamide-based polymer containing norbornadiene was aimed in this study. Aromatic group containing cyclopentadiene was synthesized primarily. Cyclopentadiene was converted to cyclopentadienyl anion through the reaction with metallic sodium. Substituent containing aryl group was linked to the 5-position of cyclopentadiene by reacting the resulting anion with halide compound. Diethyl 7-arylmethyl-2,5-norbornadiene-2,3-dicarboxylate monomer was synthesized by [4 + 2] (Diels Alder) cycloaddition reaction of substitute obtained this way with cyclopentadiene diethyl 2-butyndioate. By activating this synthesized monomer with diaminoethane, targeted polyamide-based polymer containing norbornadiene was reached. Changes in functional group in the polymerization reaction were monitored by FTIR spectroscopy technique. Moreover, in order to clarify the structure of the polymer obtained, IR and 1H NMR spectra were recorded. © 2016, Chemical Publishing Co. All rights reserved.
Description
Keywords
Energy storage, Norbornadiene, Polyamides, Quadricyclene
Journal or Series
Asian Journal of Chemistry
WoS Q Value
Scopus Q Value
Q4
Volume
28
Issue
12
