Synthesis of norbornadiene-containing polyamide based polymer
Küçük Resim Yok
Tarih
2016
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Chemical Publishing Co.
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Synthesis of polyamide-based polymer containing norbornadiene was aimed in this study. Aromatic group containing cyclopentadiene was synthesized primarily. Cyclopentadiene was converted to cyclopentadienyl anion through the reaction with metallic sodium. Substituent containing aryl group was linked to the 5-position of cyclopentadiene by reacting the resulting anion with halide compound. Diethyl 7-arylmethyl-2,5-norbornadiene-2,3-dicarboxylate monomer was synthesized by [4 + 2] (Diels Alder) cycloaddition reaction of substitute obtained this way with cyclopentadiene diethyl 2-butyndioate. By activating this synthesized monomer with diaminoethane, targeted polyamide-based polymer containing norbornadiene was reached. Changes in functional group in the polymerization reaction were monitored by FTIR spectroscopy technique. Moreover, in order to clarify the structure of the polymer obtained, IR and 1H NMR spectra were recorded. © 2016, Chemical Publishing Co. All rights reserved.
Açıklama
Anahtar Kelimeler
Energy storage, Norbornadiene, Polyamides, Quadricyclene
Kaynak
Asian Journal of Chemistry
WoS Q Değeri
Scopus Q Değeri
Q4
Cilt
28
Sayı
12
