Synthesis and characterization of s-triazine cored schiff base containing β-lactam and ıts [M(Salen/Saloph)] (M= Cr3+ and Fe3+) capped complexes
| dc.authorid | 0009-0005-3771-5856 | |
| dc.authorid | 0009-0005-8730-9573 | |
| dc.authorid | 0000-0003-1061-6143 | |
| dc.contributor.author | Caymaz, Ahmet | |
| dc.contributor.author | Mirghani, Ahmed Hamdi | |
| dc.contributor.author | Uysal, Şaban | |
| dc.date.accessioned | 2025-01-30T08:48:20Z | |
| dc.date.available | 2025-01-30T08:48:20Z | |
| dc.date.issued | 01.10.2024 | |
| dc.department | Başka Kurum | |
| dc.description.abstract | This study consists of a tripodal 6-iminopenicylanic acid ligand synthesized based on the s-triazine group and its four trinuclear complexes. For this purpose, 2,4,6-tri(p-formylphenoxy)-1,3,5-triazine (III) (TRIPOD) was obtained from the reaction of 2,4,6-trichloro-1,3,5-triazine and 4-hydroxybenzaldehyde. Then, tripodal target ligand (V) was obtained from the reaction of TRIPOD and 6-aminopenicylanic acid. Finally, tripodal trinuclear (ML) capped target complexes were obtained from the reactions of the initial complexes [(ML)2O] (M= Cr3+ or Fe3+, L= Salen or Saloph) with the target ligand in methanol media. The structures of all obtained ligands were elucidated using 1H NMR, FT-IR, and elemental analysis methods. The structures of the complexes were characterized using FT-IR, magnetic susceptibility, ICP-OES, and TGA methods. | |
| dc.description.abstract | Bu çalışma, s-triazin grubu ve onun dört trinükleer kompleksine dayalı olarak sentezlenen tripodal 6- iminopenisilanik asit ligandından oluşmaktadır. Bu amaçla 2,4,6-trikloro-1,3,5-triazin (III) (TRIPOD) ve 4- hidroksibenzaldehitin reaksiyonundan 2,4,6-tri(p-formilfenoksi)-1,3,5- triazin elde edildi. Daha sonra TRIPOD ve 6-aminopenisilanik asitin reaksiyonundan tripodal hedef ligandı (V) elde edildi. Son olarak, başlangıç komplekslerinin [(ML)2O] (M= Cr3+ veya Fe3+, L= Salen veya Saloph) metanol ortamında hedef ligand ile reaksiyonlarından tripodal trinükleer (ML) başlıklı hedef kompleksleri elde edildi. Elde edilen tüm ligandların yapıları 1H NMR, FT-IR ve elementel analiz yöntemleri kullanılarak aydınlatıldı. Komplekslerin yapıları FT-IR, manyetik duyarlılık, ICP-OES ve TGA yöntemleri kullanılarak karakterize edildi. | |
| dc.identifier.citation | Caymaz, A., Mirghani, A. H., & Uysal, Ş. (2024). Synthesis and Characterization of s-Triazine Cored Schiff Base Containing β-lactam and Its [M(Salen/Saloph)] (M= Cr3+ and Fe3+) Capped Complexes. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi, 50(2), 73-79. https://doi.org/10.35238/sufefd.1490910 | |
| dc.identifier.doi | 10.35238/sufefd.1490910 | |
| dc.identifier.endpage | 79 | |
| dc.identifier.issn | 2458-9411 | |
| dc.identifier.issue | 2 | |
| dc.identifier.startpage | 73 | |
| dc.identifier.uri | https://doi.org/10.35238/sufefd.1490910 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12395/54131 | |
| dc.identifier.volume | 50 | |
| dc.language.iso | en | |
| dc.publisher | Selçuk Üniversitesi | |
| dc.relation.ispartof | Selçuk Üniversitesi Fen Fakültesi Fen Dergisi | |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Başka Kurum Yazarı | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.subject | Metal Complexes | |
| dc.subject | Metal Kompleksleri | |
| dc.subject | Saloph | |
| dc.subject | Salen | |
| dc.subject | s-Triazine | |
| dc.subject | 6-APA | |
| dc.title | Synthesis and characterization of s-triazine cored schiff base containing β-lactam and ıts [M(Salen/Saloph)] (M= Cr3+ and Fe3+) capped complexes | |
| dc.title.alternative | β-laktam içeren s-triazin merkezli schiff bazı ve onun [M(Salen/Saloph)] (M= Cr3+ ve Fe3+) başlıklı komplekslerinin sentezi ve karakterizasyonu | |
| dc.type | Article |
