Synthesis of five new bis(amino-p-chlorophenylglyoximes) and their polymeric complexes with Ni(II), Co(II), and Cu(II)
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Dosyalar
Tarih
1994
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Marcel Dekker Inc, New York, NY, United States
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, five new bis(amino-p-chlorophenylglyoximes), 1,4-phenylene bis(amino-p-chlorophenylglyoxime); 1,1?-biphenyl-4,4?-bis(amino-p-chlorophenylglyoxime); 1,1?-diphenyloxy-4,4?-bis(amino-p-chlorophenylglyoxime); 1,1?-diphenylmethylene-4,4?-bis(amino-p-chlorophlenylglyoxime); and 1,1?-diphenylethylene-4,4?-bis(amino-p-chlorophenylglyoxime) were synthesized from anti-p-chlorophenylchloroglyoxime and the corresponding aromatic diamines. Their polymeric complexes with Ni(II), Co(II) and Cu(II) were isolated. The Ni(II) and Cu(II) complexes of these ligands are square-planar while the Co(II) complexes are octahedral with water molecules as axial ligands. 1H-NMR, AAS, IR and elemental analytical data of the complexes and ligands are discussed.
Açıklama
Anahtar Kelimeler
Kaynak
Journal of Macromolecular Science - Pure and Applied Chemistry
WoS Q DeÄŸeri
Scopus Q DeÄŸeri
Q2
Cilt
A31
Sayı
SUPPL 5
