Taç eter grubu ihtiva eden yeni vic-dioksimlerin sentezi, komplekslerinin ve özelliklerinin incelenmesi
Yükleniyor...
Dosyalar
Tarih
2006
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Selçuk Üniversitesi Fen Bilimleri Enstitüsü
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Bu çalışmada, literatürde bulunmayan üç adet yeni ligand ve bu ligandların bazı geçiş metalleri ile kompleksleri sentezlendi. Bu ligandlar; anti-4-izopropilanilin fenilaminoglioksim, anti-4-benzilpiperidinfenilaminoglioksim ve N1-(41-Benzo[15-crown- 5]naftilaminoglioksim ligandlarıdır. Çalışmanın birinci basamağında; klorofenilaminoglioksim ile 4-izopropilanilin ve 4-benzilpiperidin'in reaksiyonundan anti-4- izopropilanilinfenilaminoglioksim ile anti-4-benzilpiperidinfenilaminoglioksim ligandları sentezlendi. Ayrıca 41-aminobenzo[15-crown-5] ile 2-naftilkloroglioksim'in reaksiyonu sonucu N1-(41-Benzo[15-crown-5]naftilaminoglioksim elde edilmiştir. İkinci basamakta bu ligandların, Ni(II), Cu(II), Co(II), Cd(II), Zn(II) metal iyonlarıyla kompleksleri elde edildi. Sentezlenen ligandların ve komplekslerin yapıları 1H NMR, 13 C-NMR, IR, elementel analiz, mağnetik süsseptibilite teknikleriyle aydınlatıldı.
In this study three new ligands and their transition metal complexes were synthesized, which were not yet reported in the literature references. This ligands are; anti-4- isopropylanilinephenylaminoglyoxime, anti-4-benzylpiperidinephenylaminoglyoxime and N1- (41-Benzo[15-crown-5] naphthylaminoglyoxime. In the first part of this work. anti-4-isopropylanilinphenylaminoeglyoxime, anti-4- benzylpiperidinephenylaminoglyoxime were synthesized by the reaction of cholorophenylaminoglyoxime with 4-isoproplylaniline and 4-benzylpiperidine .In addition to this, N1-(41-Benzo[15-crown-5]naphthylaminoglyoxime was synthesized by the reaction of 4?-Aminobenzo[15-crown-5] and 2-naphthylchloroglyoxime In the second part, their Ni(II), Cu(II), Co(II), Cd(II), Zn(II) complexes were synthesized. This ligands and their complexes? structures were determined with 1H NMR, 13 C-NMR, IR, elemental analyses, magnetik succeptibiliy.
In this study three new ligands and their transition metal complexes were synthesized, which were not yet reported in the literature references. This ligands are; anti-4- isopropylanilinephenylaminoglyoxime, anti-4-benzylpiperidinephenylaminoglyoxime and N1- (41-Benzo[15-crown-5] naphthylaminoglyoxime. In the first part of this work. anti-4-isopropylanilinphenylaminoeglyoxime, anti-4- benzylpiperidinephenylaminoglyoxime were synthesized by the reaction of cholorophenylaminoglyoxime with 4-isoproplylaniline and 4-benzylpiperidine .In addition to this, N1-(41-Benzo[15-crown-5]naphthylaminoglyoxime was synthesized by the reaction of 4?-Aminobenzo[15-crown-5] and 2-naphthylchloroglyoxime In the second part, their Ni(II), Cu(II), Co(II), Cd(II), Zn(II) complexes were synthesized. This ligands and their complexes? structures were determined with 1H NMR, 13 C-NMR, IR, elemental analyses, magnetik succeptibiliy.
Açıklama
Anahtar Kelimeler
Taç eter grubu, Crown ethers group, Vic-dioximes, Vic-dioksimler
Kaynak
WoS Q Değeri
Scopus Q Değeri
Cilt
Sayı
Künye
Arslan, Ö. (2006). Taç eter grubu ihtiva eden yeni vic-dioksimlerin sentezi, komplekslerinin ve özelliklerinin incelenmesi. Selçuk Üniversitesi, Yayımlanmış yüksek lisans tezi, Konya.
