Analytic Equation of State for the Square-well Plus Sutherland Fluid from Perturbation Theory
Küçük Resim Yok
Tarih
2018
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
IRANIAN CHEMICAL SOC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Analytic expressions were derived for the compressibility factor and residual internal energy of the square-well plus Sutherland fluid. In this derivation, we used the second order Barker-Henderson perturbation theory based on the macroscopic compressibility approximation in combination with an analytical expression for radial distribution function of the reference hard sphere fluid. These properties are expressed in terms of density, temperature, and the potential parameters. Derived equations successfully applied to hard-core Lennard-Jones fluid. It is found that the agreement between theory and simulation is quite good for both the compressibility factor and the residual internal energy for a wide range of densities and temperature.
Açıklama
Anahtar Kelimeler
Equation of state, Thermodynamic properties, Square-well plus Sutherland fluid, Radial distribution function, Pair potential
Kaynak
PHYSICAL CHEMISTRY RESEARCH
WoS Q Değeri
N/A
Scopus Q Değeri
Q4
Cilt
6
Sayı
1
