Kinetics of Mercury(II) Transport Through a Bulk Liquid Membrane Containing Calix[4]arene Derivatives as Carrier

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dc.contributor.authorAlpoğuz, Hamza Korkmaz
dc.contributor.authorMemon, Shahabuddin
dc.contributor.authorErsöz, Mustafa
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T16:45:50Z
dc.date.available2020-03-26T16:45:50Z
dc.date.issued2003
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe kinetics of transport of mercury (II) ions through a bulk liquid membrane (chloroform) containing calix[4]arene nitrile derivatives as a carrier was examined at different temperatures and different stir-ring rates. The kinetics of mercury (II) transport could be analyzed in the formalism of two, consecutive, irreversible first-order reactions. The influence of temperature and stirring-rate on kinetic parameters also have been investigated. The membrane entrance rate, k(1), and the membrane exit rate, k(2), increased with increasing temperature and increasing stirring rate. For maximum membrane exit fluxes, J(a)(max), the activation energies were found as 1.923 +/- 0.15 and 2.112 +/- 0.2 kj/mol, for ligand carrier 1 and 2, respectively. The values for the found activation energy indicate that the process is controlled by species diffusion.en_US
dc.identifier.citationAlpoğuz, H. K., Memon, S., Ersöz, M., Yılmaz, M., (2003). Kinetics of Mercury(II) Transport Through a Bulk Liquid Membrane Containing Calix[4]arene Derivatives as Carrier. Separation Science and Technology, 38(7), 1649-1664. Doi: 10.1081/SS-120019098
dc.identifier.doi10.1081/SS-120019098en_US
dc.identifier.endpage1664en_US
dc.identifier.issn0149-6395en_US
dc.identifier.issue7en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1649en_US
dc.identifier.urihttps://dx.doi.org/10.1081/SS-120019098
dc.identifier.urihttps://hdl.handle.net/20.500.12395/18496
dc.identifier.volume38en_US
dc.identifier.wosWOS:000182803900011en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorAlpoğuz, Hamza Korkmaz
dc.institutionauthorMemon, Shahabuddin
dc.institutionauthorErsöz, Mustafa
dc.institutionauthorYılmaz, Mustafa
dc.language.isoenen_US
dc.publisherMarcel Dekker Incen_US
dc.relation.ispartofSeparation Science and Technologyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCo-transporten_US
dc.subjectMercury (II) transporten_US
dc.subjectTransport kineticsen_US
dc.subjectLiquid membranesen_US
dc.subjectTemperature effectsen_US
dc.subjectDiffusional rate-determining stepen_US
dc.subjectCalixarenesen_US
dc.titleKinetics of Mercury(II) Transport Through a Bulk Liquid Membrane Containing Calix[4]arene Derivatives as Carrieren_US
dc.typeArticleen_US

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