Synthesis of Amino-Substituted p-tert-Butylcalix[4]arene for the Removal of Chicago Sky Blue and Tropaeolin 000 Azo Dyes from Aqueous Environment

Basit Öğe Kaydı
dc.contributor.authorKamboh, Muhammad Afzal
dc.contributor.authorAköz, Enise
dc.contributor.authorMemon, Shahabuddin
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T18:43:40Z
dc.date.available2020-03-26T18:43:40Z
dc.date.issued2013
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractIn this study, we have reported the synthesis of new amino-substituted p-tert-butylcalix[4]arene (3) and its application for the removal of two carcinogenic azo dyes, i.e., Chicago Sky Blue (CSB) and Tropaeolin 000 (TP) from aqueous environment. The newly synthesized calix-ligand 3 is characterized by FT-IR and H-1 NMR spectroscopy as well as elemental analysis. The extraction efficiency of newly calix-ligand 3 for CSB and TP dyes from aqueous media was evaluated through liquid-liquid extraction experiments. The newly synthesized calix-ligand 3 showed outstanding extraction percentage and maximum percent extraction, i.e., 97 and 96 % of CSB and TP dyes was achieved at pH 9, respectively. During the extraction process, effect of various parameters was monitored and found that extraction is highly dependent on pH and salinity. Moreover, cyclic structure, cavity size, functional groups of the calixarene derivative, hydrophobicity, and the ionic property of guest molecules also affect the extraction efficiency. The comparative data prop up calix-ligand 3 as an effective extractant for both CSB and TP dyes.en_US
dc.description.sponsorshipScientific and Technological Research Council of TurkeyTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [2216]; Research Foundation of Selcuk University (BAP)Selcuk Universityen_US
dc.description.sponsorshipWe would like to thank The Scientific and Technological Research Council of Turkey (2216 Research Fellowship Programme For Foreign Citizens) and the Research Foundation of Selcuk University (BAP) for the financial support of this work.en_US
dc.identifier.doi10.1007/s11270-012-1424-xen_US
dc.identifier.issn0049-6979en_US
dc.identifier.issn1573-2932en_US
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s11270-012-1424-x
dc.identifier.urihttps://hdl.handle.net/20.500.12395/29869
dc.identifier.volume224en_US
dc.identifier.wosWOS:000315281300028en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGER INTERNATIONAL PUBLISHING AGen_US
dc.relation.ispartofWATER AIR AND SOIL POLLUTIONen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalixareneen_US
dc.subjectExtractionen_US
dc.subjectAzo dyesen_US
dc.subjectpHen_US
dc.titleSynthesis of Amino-Substituted p-tert-Butylcalix[4]arene for the Removal of Chicago Sky Blue and Tropaeolin 000 Azo Dyes from Aqueous Environmenten_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu