Diffusion and Selective Transport of Alkali Cations on Cation-exchange Membrane
Yükleniyor...
Dosyalar
Tarih
1995
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
MARCEL DEKKER INC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The diffusion coefficients and selective transport for alkali metal cations through a charged polysulfonated ICE-450 ion-exchange membrane were measured as a function of pH at 25 degrees C. The permeability and diffusion coefficients were found to increase in the sequence Cs+ greater than or equal to K+ > Na+ > Li+. The relationship between the permeability and the diffusion coefficients, and the hydrated radii of cations in the membrane were shown. This sequence was also explained by considering the hydration of ions in the membrane. The selectivity transport of K-Na and K-Li binary systems at various pH gradients through the membrane were also investigated under various conditions. In the selective transport of metal ions, the selectivity depended on both the hydrated ionic size and the interaction between the fixed groups in the membrane and the metal ions.
Açıklama
Anahtar Kelimeler
Kaynak
Separation Science and Technology
WoS Q Değeri
N/A
Scopus Q Değeri
Q2
Cilt
30
Sayı
18
Künye
Ersöz, Mustafa., (1995). Diffusion and Selective Transport of Alkali Cations on Cation-exchange Membrane. Separation Science and Technology, 30(18), 3523-3533. DOI: 10.1080/01496399508015133
