Column Chromatography and Kinetics of Nucleosides and Nucleic-Acid Bases on Immobilized Nickel-Cdae-Sporopollenin and Cobalt-CDAE-Sporopollenin

dc.contributor.authorPehlivan, Erol
dc.contributor.authorYıldız, Salih
dc.date.accessioned2020-03-26T16:24:22Z
dc.date.available2020-03-26T16:24:22Z
dc.date.issued1994
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractSporopollenin, a natural polymer, has been modified for application as a ligand-exchange material. The ligand-exchange chromatography with the functionalized Lycopodium clavatum is a useful method for the rapid separation of nucleosides and nucleic acid bases. The synthesis of tris(carboxymethyl) ethylene diamine Lycopodium clavatum has been described. The resin contained functional diaminoethane and carboxyl groups. Nickel(II) and cobalt(II) metal ions can easily be immobilized on this carboxylated-diamino-ethyl (CDAE)-sporopollenin. Physicochemical and chelating properties of Lycopodium clavatum have been studied extensively. Ligand-exchange chromatography of CDAE-sporopollenin has also been compared to the conventional synthetic chelex-100 resin. The kinetics of cytidine in CDAE-sporopollenin resin has been investigated. The rate measurements have been made by a potentiometric technique. The relative rates at which nucleosides bind to the resin are determined by the actual chemical-exchange reaction between ligands and resin.en_US
dc.identifier.citationPehlivan, E., Yıldız, S., (1994). Column Chromatography and Kinetics of Nucleosides and Nucleic-Acid Bases on Immobilized Nickel-Cdae-Sporopollenin and Cobalt-CDAE-Sporopollenin. Separation Science and Technology, 29(7), 887-95. DOI: 10.1080/01496399408006632
dc.identifier.doi10.1080/01496399408006632en_US
dc.identifier.endpage895en_US
dc.identifier.issn0149-6395en_US
dc.identifier.issue7en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage887en_US
dc.identifier.urihttps://dx.doi.org/10.1080/01496399408006632
dc.identifier.urihttps://hdl.handle.net/20.500.12395/16196
dc.identifier.volume29en_US
dc.identifier.wosWOS:A1994NJ76200006en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorPehlivan, Erol
dc.institutionauthorYıldız, Salih
dc.language.isoenen_US
dc.publisherMARCEL DEKKER INCen_US
dc.relation.ispartofSeparation Science and Technologyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleColumn Chromatography and Kinetics of Nucleosides and Nucleic-Acid Bases on Immobilized Nickel-Cdae-Sporopollenin and Cobalt-CDAE-Sporopolleninen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Yükleniyor...
Küçük Resim
İsim:
pehlivan1994 (1).pdf
Boyut:
373 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Makale Dosyası