Properties and Synthesis of the Cr(III)-Salen/Salophen Complexes Containing Triphenylamine Core

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dc.contributor.authorKocyigit, Ozcan
dc.date.accessioned2020-03-26T18:31:08Z
dc.date.available2020-03-26T18:31:08Z
dc.date.issued2012
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractTwo triphenylamine derivatives bearing 4-aminobenzoic acid and 5-aminoisophthalic acid were synthesized. Then, the prepared triphenylamine derivatives were reacted with two new Cr(III) complexes involving tetradenta Schiff bases N,N-bis(salicylidene)ethylenediamine or bis(salicylidene)-o-phenylenediamine. The structures of these compounds were characterized by elemental analysis, FT-IR, TG, H-1 NMR, and C-13 NMR techniques and magnetic susceptibility measurement. The complexes can also be characterized as low-spin distorted octahedral Cr(III) bridged by carboxylic acids. The carboxylic acids play a role as bridges for weak antiferromagnetic intramolecular exchange. Also, the UV spectra of these derivatives revealed that the maximum wavelengths of the complexes are shifted, compared with the ligands.en_US
dc.description.sponsorshipScientific Research Projects Foundation of Selcuk University (SUBAP)Selcuk University; Technical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)en_US
dc.description.sponsorshipThe author would like to thank the Scientific Research Projects Foundation of Selcuk University (SUBAP) and Technical Research Council of Turkey (TUBITAK) for financial support of this work. He also thanks Serkan Erdemir for assistance in the preparation of the manuscript.en_US
dc.identifier.doi10.1080/15533174.2011.609517en_US
dc.identifier.endpage204en_US
dc.identifier.issn1553-3174en_US
dc.identifier.issn1553-3182en_US
dc.identifier.issue2en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage196en_US
dc.identifier.urihttps://dx.doi.org/10.1080/15533174.2011.609517
dc.identifier.urihttps://hdl.handle.net/20.500.12395/28339
dc.identifier.volume42en_US
dc.identifier.wosWOS:000303588700009en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTAYLOR & FRANCIS INCen_US
dc.relation.ispartofSYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectcomplexationen_US
dc.subjectSchiff baseen_US
dc.subjectsynthesisen_US
dc.subjecttriphenylaminen_US
dc.titleProperties and Synthesis of the Cr(III)-Salen/Salophen Complexes Containing Triphenylamine Coreen_US
dc.typeArticleen_US

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