Covalent grafting of three flavonoids onto the glassy carbon electrode surface by cyclic voltammetry
Küçük Resim Yok
Tarih
2011
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
WALTER DE GRUYTER GMBH
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Electrochemical oxidation of quercetin (QR), 3-hydroxyfl avone (3HF), and baicalein (BN) and their grafting onto the glassy carbon (GC) electrode have been studied using the cyclic voltammetric (CV) technique. Electrochemical studies were performed within a one-compartment three-electrode cell at room temperature. The modification was carried out only in nonaqueous media, while the electrochemical characterization was done in both aqueous and nonaqueous media. In the nonaqueous experiments, 0.1 m tetrabutylammonium tetrafluoroborate in acetonitrile was used, whereas in the aqueous experiments, Britton-Robinson buffer solutions (pH = 2) and 0.1 m KCl solutions were. Surface modifi cations were performed by CV for all compounds. The presence of QR, 3HF, and BN at the GC electrode surface was characterized by CV, electrochemical impedance spectroscopy, contact angle measurement, ellipsometry, and atomic force microscopy.
Açıklama
Anahtar Kelimeler
favonoid, electrochemical modification, surface characterization, contact angle measurements, ellipsometric thickness.
Kaynak
REVIEWS IN ANALYTICAL CHEMISTRY
WoS Q Değeri
Q4
Scopus Q Değeri
Q2
Cilt
30
Sayı
03.04.2020
