Transport of Hg2+ Through Bulk Liquid Membrane Using a Bis-Calix[4]Arene Nitrile Derivative as Carrier: Kinetic Analysis

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dc.contributor.authorAlpoğuz, Hamza Korkmaz
dc.contributor.authorMemon, Shahabuddin
dc.contributor.authorErsöz, Mustafa
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T16:44:55Z
dc.date.available2020-03-26T16:44:55Z
dc.date.issued2002
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe transport of Hg(II) ions from an aqueous solution into an aqueous receiving solution through a bulk liquid membrane containing a bis-calix[4]arene nitrile derivative (1) as a carrier was examined. The kinetic parameters were analyzed assuming two consecutive, irreversible first-order reactions. The influence of temperature, the solvent and stirring rate on the kinetic parameters (k(1), k(2), R-m(max), t(max), J(d)(max), J(a)(max)) has also been investigated. The membrane entrance rate, k(1), and the membrane exit rate, k(2), increased with increasing temperature and stirring rate. The membrane entrance and exit rate constants are found to vary in the order CH2Cl2 > CHCl3 > CCl4. For the maximum membrane exit flux, Jamax, the activation energy was found from the slope of the linear Arrhenius relationship to be 9.95 kcal mol(-1), which indicates that the process is controlled by species diffusion.en_US
dc.identifier.citationAlpoğuz, H. K., Memon, S., Ersöz, M., Yılmaz, M., (2002). Transport of Hg2+ Through Bulk Liquid Membrane Using a Bis-Calix[4]Arene Nitrile Derivative as Carrier: Kinetic Analysis. New Journal of Chemistry, (26), 477-480. Doi: 10.1039/b106225p
dc.identifier.doi10.1039/b106225pen_US
dc.identifier.endpage480en_US
dc.identifier.issn1144-0546en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage477en_US
dc.identifier.urihttps://dx.doi.org/10.1039/b106225p
dc.identifier.urihttps://hdl.handle.net/20.500.12395/18085
dc.identifier.volume26en_US
dc.identifier.wosWOS:000174726600020en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorMemon, Shahabuddin
dc.institutionauthorErsöz, Mustafa
dc.institutionauthorYılmaz, Mustafa
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofNew Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleTransport of Hg2+ Through Bulk Liquid Membrane Using a Bis-Calix[4]Arene Nitrile Derivative as Carrier: Kinetic Analysisen_US
dc.typeArticleen_US

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