Preparation of polymer inclusion membrane with sodium diethyldithiocarbamate as a carrier reagent for selective transport of zinc ions

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dc.contributor.authorArslan, Gülsin
dc.contributor.authorYılmaz, Abdurrahman
dc.contributor.authorTor, Ali
dc.contributor.authorErsöz, Mustafa
dc.date.accessioned2020-03-26T19:42:22Z
dc.date.available2020-03-26T19:42:22Z
dc.date.issued2017
dc.departmentSelçuk Üniversitesien_US
dc.descriptionMembrane Science and Technology Conference of Visegrad Countries (PERMEA) / Membrane and Electromembrane Processes Conference (MELPRO) -- MAY 15-19, 2016 -- Prague, CZECH REPUBLICen_US
dc.description.abstractThis study reports the design of a new type of polymer inclusion membrane (PIM) for selective transport of zinc ion. Sodium diethyldithiocarbamate (NaDDTC) was incorporated in the cellulose acetate-based membrane as a carrier for Zn(II) ion. The PIMs were characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, atomic force microscopy and contact angle measurements. The effects of parameters, including concentration of Zn(II) in the feed phase, HCl in the stripping phase and amount of NaDDTC incorporated in the membrane, on the transport of Zn(II) ion were studied. For 1 x 10(-4) M of Zn(II) ion in the feed phase at pH 5.04, 96% of Zn(II) ion was transported through the PIMs prepared with 1.0 (wt%) diethyldithiocarbamate via 0.5 M HCl as a stripping phase. The diffusion of Zn(II) ions through the membrane was governed by complex formation between Zn(II) ion and NaDDTC in the membrane. Moreover, selective transport of Zn(II) ion was achieved in the presence of divalent metal ions involving Cu(II), Pb(II) and Ni(II). The prepared PIM provided reproducible transport efficiency, and it can be efficiently used in separation processes.en_US
dc.description.sponsorshipSelcuk University Research Foundation (SUAF)Selcuk Universityen_US
dc.description.sponsorshipThe authors are thankful to Selcuk University Research Foundation (SUAF) for the financial support.en_US
dc.identifier.doi10.5004/dwt.2017.20485en_US
dc.identifier.endpage356en_US
dc.identifier.issn1944-3994en_US
dc.identifier.issn1944-3986en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage348en_US
dc.identifier.urihttps://dx.doi.org/10.5004/dwt.2017.20485
dc.identifier.urihttps://hdl.handle.net/20.500.12395/35399
dc.identifier.volume75en_US
dc.identifier.wosWOS:000404396100040en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherDESALINATION PUBLen_US
dc.relation.ispartofDESALINATION AND WATER TREATMENTen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectPolymer inclusion membraneen_US
dc.subjectFacilitated transporten_US
dc.subjectZincen_US
dc.subjectSodium diethyldithiocarbamateen_US
dc.titlePreparation of polymer inclusion membrane with sodium diethyldithiocarbamate as a carrier reagent for selective transport of zinc ionsen_US
dc.typeArticleen_US

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