Dual-channel fluorescent probe based on bisphenol A-rhodamine for Zn2+ and Hg2+ through different signaling mechanisms and its bioimaging studies

dc.contributor.authorErdemir, Serkan
dc.contributor.authorYuksekogul, Mesut
dc.contributor.authorKarakurt, Serdar
dc.contributor.authorKocyigit, Ozcan
dc.date.accessioned2020-03-26T19:34:59Z
dc.date.available2020-03-26T19:34:59Z
dc.date.issued2017
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA novel dual channel probe based on bisphenol A-rhodamine (BAR) was successfully designed and synthesized with high selectivity and sensitivity to Zn2+ and Hg2+ ions. BAR exhibited an effectively selective and sensitive recognition toward Zn2+ and Hg2+ ions through two different mechanisms (i.e. ESIPT and FRET) in pure MeCN and MeCN-H2O (v/v = 8/2, 5 mM, HEPES, pH 7.0) over other cations. The complexation properties of BAR with Zn2+ and Hg2+ ions were examined by H-1 NMR, C-13 NMR and FTIR experiments. The detection limits for Zn2+ and Hg2+ were 2.21 and 2.16 mu M, respectively. Furthermore, possible utilization of BAR as bio-imaging fluorescent probe to detect Hg2+ in human prostate cancer cell lines was ;also observed by Fluorescent Cell Imager. (C) 2016 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipResearch Foundation of Selcuk University (SUBAP-Grant) [15401051]en_US
dc.description.sponsorshipWe thank the Research Foundation of Selcuk University (SUBAP-Grant no. 15401051) for its financial support of this work produced from a part of M. Yuksekogul's MSc Thesis.en_US
dc.identifier.doi10.1016/j.snb.2016.10.082en_US
dc.identifier.endpage238en_US
dc.identifier.issn0925-4005en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage230en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.snb.2016.10.082
dc.identifier.urihttps://hdl.handle.net/20.500.12395/34985
dc.identifier.volume241en_US
dc.identifier.wosWOS:000393253700029en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE SAen_US
dc.relation.ispartofSENSORS AND ACTUATORS B-CHEMICALen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectBisphenol Aen_US
dc.subjectRhodamineen_US
dc.subjectTurn onen_US
dc.subjectZincen_US
dc.subjectMercuryen_US
dc.titleDual-channel fluorescent probe based on bisphenol A-rhodamine for Zn2+ and Hg2+ through different signaling mechanisms and its bioimaging studiesen_US
dc.typeArticleen_US

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