Push-pull type material having spirobifluorene as pi-spacer for dye sensitized solar cells

Küçük Resim Yok

Tarih

2016

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

PERGAMON-ELSEVIER SCIENCE LTD

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Two organic dyes for dye-sensitized solar cells (DSSC) based on spirobifluorene were synthesized and characterized. Electrochemical, spectroscopic and photovoltaic properties of the dyes have been investigated. Hexyloxy substituted triarylamine was used as electron donating moiety in the molecule while spirobifluorene and cyanoacrylic acid were used as pi-bridge and acceptor groups, respectively. MK162-sensitized solar cells exhibited a short-circuit current (I-SC) of 4,92 mA cm(-2), an open-circuit voltage (V-OC) of 520 mV and a fill factor (FF) of 0.59, resulting an overall power conversion efficiency of 1,52 where the reference cell, Z907 was yielded an overall conversion efficiency of 4.08% efficiency with 620 mV of V-OC and 14.51 mA cm(-2) of Isc under standard AM 1.5 illumination. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Açıklama

Anahtar Kelimeler

Donor-acceptor dyes, pi-bridge effect, Dye sensitized solar cell

Kaynak

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

WoS Q Değeri

Q1

Scopus Q Değeri

Q1

Cilt

41

Sayı

46

Künye