New tridentate azo-azomethines and their copper(II) complexes: Synthesis, solvent effect on tautomerism, electrochemical and biological studies

Basit Öğe Kaydı
dc.contributor.authorSarigul, Munire
dc.contributor.authorDeveci, Pervin
dc.contributor.authorKose, Muhammet
dc.contributor.authorArslan, Ugur
dc.contributor.authorDagi, Hatice Turk
dc.contributor.authorKurtoglu, Mukerrem
dc.date.accessioned2020-03-26T19:06:27Z
dc.date.available2020-03-26T19:06:27Z
dc.date.issued2015
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractIn this study, three azo-azomethines and their copper(II) complexes were prepared and characterized by analytical and spectroscopic methods. The complexes prepared were found to be mononuclear and the chelation of the ligands to the copper(II) ions occurs through two phenolic oxygens and a nitrogen atom of the azomethine group of the ligand. The tautomeric behaviors of the azo-azomethines in solution were studied by UV-Vis. spectra in three organic solvents with different polarity (CHCl3, DMSO and DMF) at room temperature. The redox behaviors of the azo-azomethines and their Cu(II) complexes were investigated by cyclic voltammetry (CV) in DMSO solution containing 0.1 M tetrabutylammonium tetrafluoroborate (TBATFB) as supporting electrolyte. Additionally, the antibacterial activity was also evaluated by the broth microdilution methods against Staphylococcus aureus, Enterococcus faecalis, Escherichia coli, Klebsiella pneumoniae and Pseudomonas aeruginosa. The compounds were found to be less effective against all bacteria tested than two reference antibiotics (ampicillin and gentamicin). (C) 2015 Elsevier B.V. All rights reserveden_US
dc.identifier.doi10.1016/j.molstruc.2015.04.043en_US
dc.identifier.endpage73en_US
dc.identifier.issn0022-2860en_US
dc.identifier.issn1872-8014en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage64en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.molstruc.2015.04.043
dc.identifier.urihttps://hdl.handle.net/20.500.12395/32363
dc.identifier.volume1096en_US
dc.identifier.wosWOS:000356550000008en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIERen_US
dc.relation.ispartofJOURNAL OF MOLECULAR STRUCTUREen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectAzo-azomethinesen_US
dc.subjectTautomeren_US
dc.subjectCopper(II) complexesen_US
dc.subjectSolvent effecten_US
dc.subjectCyclic voltammetryen_US
dc.subjectAntibacterial activityen_US
dc.titleNew tridentate azo-azomethines and their copper(II) complexes: Synthesis, solvent effect on tautomerism, electrochemical and biological studiesen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu